Results 21 to 30 of about 6,206 (212)

Electrode and Microstructure Dependence of Oxygen Diffusion in Ferroelectric Hafnium Zirconium Oxide Thin Films

open access: yesAdvanced Functional Materials, EarlyView.
Significant nanoscale oxygen diffusion coefficient variations are measured in ferroelectric hafnium zirconium oxide films with grain boundaries and electrode interfaces exhibiting values 104 times larger than the grain cores. Overall coefficients are 10X larger for films prepared with metal nitride electrodes compared to refractory metals. New insights
Liron Shvilberg   +6 more
wiley   +1 more source

Resolving the Cu(bdc) Conundrum: Identifying Non‐Porous Packing of Prototypical Coordination‐Network Thin Films Combining Advanced Diffraction Techniques and Computational Modelling

open access: yesAdvanced Functional Materials, EarlyView.
Solution‐processed Cu(bdc) forms prototypical MOF thin films for which a multitude of not fully satisfactory structural models have been suggested. Combining rotating grazing‐incidence diffraction and X‐ray reflectivity on two complementary samples with density‐functional theory, we first discard the previously suggested models and then identify a non ...
Narges Taghizade   +7 more
wiley   +1 more source

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur   +3 more
wiley   +1 more source

Electrocapillary Modulated Interfacial Tension Amplifies Liquid Metal Transduction

open access: yesAdvanced Functional Materials, EarlyView.
This study presented an electrocapillary‐enhanced magnetohydrodynamic pumping strategy that harnesses the Lorentz force and interfacial tension modulation of liquid metal droplets to achieve amplified fluidic power. The system enabled low‐voltage, self‐oscillating fluidic transduction with enhanced pressure and flow generation, supporting compact ...
Saba Firouznia   +3 more
wiley   +1 more source

Anion‐Exchange‐Enabled Hydrogel Electrolytes With High Zn2+ Transference for Dendrite‐Free Flexible Zinc‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A high‐Zn2+‐transference hydrogel electrolyte of ex‐PDADAM is developed via anion exchange at quaternary ammonium sites, achieving high Zn2+ transference number (0.86), ionic conductivity (8.10 mS cm−1), and toughness (51.25 MJ m−3). Symmetric cells are operated stably for over 2000 h, while flexible pouch cells retain 90.9% capacity after 300 cycles ...
Jung Woo Hong   +8 more
wiley   +1 more source

Surprising Water Slipping Performance on Highly Hydrophilic PEG‐Derived Monolayer‐Covered Surfaces: Preparation, Mechanism, and Application

open access: yesAdvanced Functional Materials, EarlyView.
Highly hydrophilic surfaces (water contact angle, ≈17.7°) exhibiting surprising water slipping performance (sliding angle, ≈7.3°) are successfully prepared via simple chemisorption of polyethylene glycol (PEG) organosilane and subsequent alkali‐treatment.
Hyeonjin Kim   +5 more
wiley   +1 more source

Engineering MnNiPx Cathode via Dual Role of Mn: Simultaneous Enhancement of Activity and Intermittent Operation Durability

open access: yesAdvanced Functional Materials, EarlyView.
Engineering MnNiPx cathodes through the dual role of Mn simultaneously improves hydrogen evolution reaction activity and intermittent‐operation durability. Mn preferentially oxidizes to protect Ni–P sites from irreversible oxidation, while metallic Mn incorporation enhances the HER kinetics of Ni–P active layer.
Ik‐Sun Kim   +16 more
wiley   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

Polymer‐Redox Interactions Enhance Ferro/Ferricyanide Thermogalvanic Cells

open access: yesAdvanced Functional Materials, EarlyView.
Polyelectrolyte could modify the hydration structure of the redox couple in solution and improve the output performance of thermogalvanic cells, providing new fundamental insight into how electrostatic interactions can be exploited to tailor thermoelectric properties.
Pedro Santos Candiotto de Oliveira   +6 more
wiley   +1 more source

Scandium-containing layered hydroxides

open access: yesRussian Journal of Inorganic Chemistry, 2007
A scandium analogue of hydtotalcite and a mixed sample containing both scandium and aluminum have been synthesized and characterized. It is known that both samples have a layered structure; the unit cell parameters of the scandium-containing samples are slightly higher than the respective values of an ordinary aluminum-containing ...
Vorontsova, O. A.   +2 more
openaire   +2 more sources

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