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Li–S batteries: Firing for compactness
Nature Energy, 2017Conventional Li–S batteries have a non-compact cathode structure containing low areal loading of active materials. Now, a strategy of burning Li foils in a CS2 vapour is presented, which leads to the formation of highly compact Li2S nanoparticles as a lithiated sulfur cathode, offering promising battery performance.
Yanguang Li, Fengjiao Chen
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Advanced Planar Li-S Batteries
ECS Meeting Abstracts, 2016Ceramatec is developing new batteries that make use of a non-porous, high ion conductivity ceramic membrane employing a lithium-sulfur (Li-S) battery chemistry. Porous separators found in today’s batteries contain liquids that negatively impact cycle life.
Feng Zhao +3 more
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The Role of Metal Disulfide Interlayer in Li–S Batteries
The Journal of Physical Chemistry C, 2017Recently many observations related to the catalytic effects of layered metal disulfide versus polysulfide electrochemistry were documented. In this work, we investigated the reactivity of layered WS2 in a Li-S battery and observed a chemical reaction involving the removal of W ions by polysulfides. The presence of metallic tungsten nanoparticles in the
Andrea Paolella +16 more
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Outline of Li–S Battery Project
2021In this project, Li–S batteries have been investigated by a team comprising 12 principal investigators. In particular, we focused on developing Li–S batteries with sparingly solvating electrolytes for cathode active materials. Prior to the start of our project, the dissolution of the discharge products of sulfur (lithium polysulfides: Li2Sx, x = 8 ~ 2)
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Equivalent Circuit Modelling of Li-S Batteries
ECS Transactions, 2021The presented article describes a Multi-Scale Multi-Domain model of a Li-S battery using an equivalent circuit model consisting of R-C pairs. The parameters of the equivalent circuit model were obtained by fitting experimentally measured results from electrochemical impedance spectroscopy at various states of charge.
Martin Mačák +3 more
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In Situ Techniques for Developing Robust Li–S Batteries
Small Methods, 2018AbstractRechargeable lithium–sulfur batteries (LSBs) are of great interest in the field of energy storage due to their favorable operational characteristics, for example, high theoretical energy density and low cost. However, LSBs are limited by long‐term degradation, caused by the dissolution of intermediate lithium polysulfide phases.
Ming Li +7 more
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Engineering Cooperative Catalysis in Li–S Batteries
Advanced Energy Materials, 2023AbstractLithium–sulfur (Li–S) batteries are regarded to be one of the most promising next‐generation batteries owing to the merits of high theoretical capacity and low cost. However, the aprotic S electrochemistry is hampered by the shuttling effect and sluggish conversion of soluble lithium polysulfides (LiPSs).
Jinlei Qin +3 more
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Is overprotection of the sulfur cathode good for Li–S batteries?
Chemical Communications, 2015Moderate dissolution of polysulfides in the electrolyte is indispensable for the high-efficiency and stable discharge/charge cycling of Li–S batteries.
Tian, Gao +7 more
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Li-S Batteries at a Crossroads
ECS Meeting Abstracts, 2016This talk will provide an overview of Li-S batteries, including conventional liquid cells and the important advances that have been made in understanding the chemistry and improving upon it, and will address new opportunities in solid state sulfur cells.
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Electrospinning of Nanofibers for Li–S Battery
2020Li-ion batteries have been widely used in portable electronic devices owing to their excellent assets such as high energy/power density and long operating life. There is an urgent demand to develop high-performance electrode materials with the high capability to store and distribute energy more effectively to additional boost the performance of LIBs ...
Shengjie Peng, P. Robert Ilango
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