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Revisiting the Role of Polysulfides in Lithium–Sulfur Batteries
AbstractIntermediate polysulfides (Sn, where n = 2–8) play a critical role in both mechanistic understanding and performance improvement of lithium–sulfur batteries. The rational management of polysulfides is of profound significance for high‐efficiency sulfur electrochemistry.
Gäoran Li, Shun Wang, Yining Zhang
exaly +4 more sources
Interaction Mechanisms between Lithium Polysulfides/Sulfide and Small Organic Molecules. [PDF]
Lithium polysulfides (LiPSs)/sulfide are essential in secondary lithium batteries. In this work, we used density functional theory computational methods to obtain the law of constraining lithium polysulfides/sulfide by the affinitive interactions at the ...
Zhang J, Yang J, Liu Z, Zheng B.
europepmc +2 more sources
Effect of properties of carbon materials on specific energy and cycling of lithium-sulfur batteries [PDF]
The effect of the structure and the specific surface area of carbon materials, contained in positive electrodes, on the peculiarities of cycling of lithium-sulfur cells (the depth of electrochemical reduction of sulfur and lithium polysulfides, the ...
Karaseva, Elena Vladimirovna +3 more
doaj +1 more source
Lithium-sulfur (Li-S) and lithium-selenium (Li-Se) batteries are both facing the cathode issues of low Coulombic efficiency and unstable cycling stability due to the severe shuttle effect of lithium polysulfides or lithium polyselenides.
Xingxing Gu, Lan Deng, Xiaolei Ren
doaj +1 more source
A Nafion protective layer for stabilizing lithium metal anodes in working lithium–sulfur batteries
Lithium–sulfur batteries are promising next‐generation energy storage devices due to their ultrahigh theoretical energy density. However, the parasitic reactions between lithium polysulfides and lithium metal anodes render lithium anodes extremely ...
Zheng Li +8 more
doaj +1 more source
The development of low‐temperature lithium–sulfur batteries (LSB) has been suppressed by rather poor sulfur utilization and cycle performance, caused by planar Li2S growth, hindered lithium polysulfides (LiPSs) transformation, and poor stability of the ...
Zeng Guan +6 more
semanticscholar +1 more source
High theoretical energy density endows lithium–sulfur batteries to be a promising candidate of the secondary batteries. Numerous studies have been implemented relying on exploring efficient host materials or separator modifying layers to solve the ...
Zhiyuan Pang +7 more
doaj +1 more source
Lithium-sulfur batteries suffer from the shuttle effect of lithium polysulfides and interfacial instability of the lithium metal anode. Here, the authors use 1,3,5-benzenetrithiol as an electrolyte additive to protect sulfur cathode and lithium metal ...
Wei Guo +5 more
doaj +1 more source
Visualization of polysulfide dissolution in lithium-sulfur batteries using in-situ NMR microimaging
Lithium-sulfur batteries offer the highest theoretical energy density among enclosed rechargeable batteries. However, there are various issues that need to be addressed before their practical adoption, such as the dissolution of intermediate lithium ...
Arunkumar Dorai +2 more
doaj +1 more source
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth [PDF]
Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and ...
Li, Weiyang +6 more
openaire +4 more sources

