Results 111 to 120 of about 5,247,137 (297)

Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks

Advanced Functional Materials, EarlyView.
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie, Rui Guo, Zhen Liu, Yang Hu, Laichun Zhao, Omid Mazaheri, Bufeng Zhang, Shuaijun Pan   +7 more
wiley   +1 more source

Constructing a Phosphating-Nitriding Interface for Practically Used Lithium Metal Anode

, 2020
Low cycling reversibility and safety concerns are hindering the practical application of high-energy lithium metal batteries. Rational design of an artificial electrode/electrolyte interface is regarded as an effective way to circumvent the above ...
Liu, Qilei, Ling, Min, Zhang, Weidong, Fan, Lei, Wang, Linyan, Wu, Qian, Shen, Zeyu, Li, Siyuan, Wang, Xinyang, Lu, Yingying   +9 more
core   +1 more source

Unveiling Solid Electrolyte Interphase Formation at the Molecular Level: Computational Insights into Bare Li-Metal Anode and Li₆PS_5-xSe_xCl Argyrodite Solid Electrolyte. [PDF]

ACS Energy Lett, 2023
Golov A, Carrasco J.
europepmc   +1 more source

Architecture‐Driven Functional Coupling in Vertically Aligned Nanocomposites

Advanced Functional Materials, EarlyView.
Vertically aligned nanocomposites define a growth‐engineered architecture in which vertical interfaces, strain fields, defect pathways, and phase connectivity are created simultaneously. This review shows how these architectural features couple ferroic, optical, ionic, electrochemical, and device responses, establishing design rules and open challenges
Md Shatil Islam‐Shanto, Javier Zamudio‐García, Abraham Sánchez‐Caballero, David Marrero‐López, Vincenzo Esposito   +4 more
wiley   +1 more source

Decoupling the Size and Loading Effects in Silver Nanoparticles for Efficient Paired Carbon Dioxide and Formaldehyde Electrolysis

Advanced Functional Materials, EarlyView.
We investigate size‐dependent CO selectivity on Ag nanoparticles, where optimized Ag loading achieves nearly 100% Faradaic Efficiency for CO at −100 mA·cm−2. In situ SERS and XPS reveal the crucial role of optimized loading in catalytic performance. The Ag/C catalyst further exhibits bifunctional activity, enabling efficient electrolysis of CO2 and ...
Venkata S. R. K. Tandava, Clara Große, Debabrata Bagchi, Zhenye Zhu, Suptish Ghosh, J. Niklas Hausmann, Carsten Walter, Rosario Suarez Anzorena, Catalina Elena Jimenez, Yasmin Lucero Cobos‐Becerra, Jack C. Q. Fletcher, Tobias Sontheimer, Michael Schwarze, Holger Dau, Matthias Driess, Marcus Bär, Prashanth W. Menezes   +16 more
wiley   +1 more source

Highly stable Li+ deposition guided by a lithiophilic microchannel

Materials Reports: Energy
The repeated volume variation of lithium (Li) metal anode (LMA) upon Li+ plating/stripping, the volatile interface between Li and the electrolyte, and the incessant growth of Li dendrites on Li metal surface have severely hindered the practical ...
Fuliang Xu, Shuling Fan, Zhongcheng Sun, Yang Peng, Qikai Wang, Fangmin Ye   +5 more
doaj   +1 more source

Stereometric Molecular Engineering for Ultra‐Stable Aqueous Zinc‐Ion Batteries

Advanced Functional Materials, EarlyView.
Stereochemical configuration of molecular additives greatly influences interfacial adsorption at the Zn surface. The optimal tilted dual‐anchored adsorption geometry of myo‐inositol constructs a water‐deficient interface and regulates the solvation structure.
Cunxin Liu, Peng Yang, Mohamed H. Helal, Jiang Zhou, Eero Kontturi   +4 more
wiley   +1 more source

Optimizing NiMo Electrocatalyst Coatings for Hydrogen Evolution in Alkaline Electrolysis With The Machine Learning‐Guided Autonomous Platform CatBot

Advanced Functional Materials, EarlyView.
This work presents a closed‐loop optimization workflow integrating CatBot, an automated synthesis and testing system, to discover NiMo hydrogen‐evolution catalysts. CatBot synthesised and evaluated 228 unique samples, identifying the best performing catalysts for transfer to nickel‐foam electrodes. The best candidate is highly active, reaching 1 Acm−2${
Paolo Vincenzo Freiesleben de Blasio, Jonas Elsborg, Elif Coşkun, Andreas Burger, Pradipkumar Manubhai Leuaa, Thu Pham Anh Phan, Jin Hyun Chang, Christodoulos Chatzichristodoulou   +7 more
wiley   +1 more source

Effects of LLZO Microstructure Porosity, LLZO/Li‐Metal Interfacial Polarization Resistance, and Applied Areal Current Density on Li‐Metal Dendrite Formation in LLZO Bilayer Symmetric Cells

Advanced Functional Materials, EarlyView.
The effects of solid‐state electrolyte architecture and electrolyte/electrode interfacial polarization resistance on Critical Current Density and the risks for “interfacial” and “internal” Li‐metal dendrite formation were investigated in simulations of FIB‐reconstructed porous‐dense Li7La3Zr2O12 (LLZO) “bilayers”, providing insight for full cells ...
Tanner R. Hamann, Jon O'Neill, Eric D. Wachsman   +2 more
wiley   +1 more source

Dendrite-Free Li Metal Anode for Rechargeable Li–SO₂ Batteries Employing Surface Modification with a NaAlCl₄–2SO₂ Electrolyte

, 2018
Dendritic growth of a Li metal anode during cycling is one of major issues to be addressed for practical application of Li metal rechargeable batteries. Herein, we demonstrate that surface modification of Li metal with a Na-containing SO2 electrolyte can
Hyun Jong Kim (5786426), Ayoung Kim (5786420), Hansu Kim (1427107), Young-Jun Kim, Jaehwan Chun (5786417), Hyun Jong Kim, Ayoung Kim, Young-Jun Kim (696507), Hojae Jung, Goojin Jeong (1458946), Hojae Jung (5786423), Goojin Jeong, Juhye Song (1458949), Hansu Kim, Jaehwan Chun, Juhye Song   +15 more
core   +1 more source