Multi‐Li+ Coordination for Superior Room‐Temperature Ionic Conductivity in PEO Solid Electrolytes
A phosphonate‐functionalized polycarboxylate ether (P‐PCE) is introduced into PEO electrolytes to induce multi‐Li+ ions coordination, which effectively dissociates lithium salts, liberates Li+ from the strong chelation by PEO chains, and promotes fast Li+ hopping between adjacent coordination sites. Simultaneously, this design establishes dynamic, high‐
Hengming Yan +11 more
wiley +1 more source
Concentration-Driven Li<sup>+</sup> Solvation Engineering with TDMAP-Based Porphyrin Additives for Dendrite-Free Li Metal Batteries. [PDF]
Afzali P +5 more
europepmc +1 more source
Phase‐Engineered MoS2 Quantum Monolayer Catalysts
A new type of catalyst model—phase‐engineered MoS2 quantum‐monolayer catalyst (∼0.8 nm thick, < 6 nm in the lateral size; switchable freely among metallic 1T, semiconducting 2H, and a hybrid phase of metallic‐semiconducting 1T‐2H)—is reported. It can efficiently and stably drive photochemical H2, syngas and ammonia synthesis as a catalyst or co ...
Ruijie Yang +12 more
wiley +1 more source
High-Entropy Phosphide-Polymer Nanointerfaces Enable Adaptive Li<sup>+</sup> Transport for High-Performance Solid-State Li Metal Batteries. [PDF]
Zhang J +9 more
europepmc +1 more source
Metal-oxygen bonds: stabilizing the intermediate species towards practical Li-air batteries
Rechargeable nonaqueous Li-air batteries are attracting much attention due to their far higher theoretical energy density than lithium-ion batteries. However, Li-air batteries suffers from poor round-trip efficiency, low rate capability and poor cycle ...
Lili Liu (20116599) +7 more
core
Descriptor‐Informed Screening of Interface‐Active Molecules for Efficient Magnesium Metal Anodes
A descriptor‐informed molecular screening strategy identifies 4‐bromo‐N, N‐dimethylaniline (BrNNA) as an interface‐active electrolyte component that enables fast Mg stripping/plating in Mg(TFSI)2‐based electrolytes. By simultaneously regulating Mg2+ solvation and interphase formation, the BrNNA‐containing electrolyte delivers activation‐free Mg ...
Hao Xu +16 more
wiley +1 more source
High-energy anode-free Li metal batteries with in-built surface-fluorinated Li-rich Mn-based cathodes. [PDF]
Hu W +14 more
europepmc +1 more source
Charge Storage and Dark Photocatalysis in Multivariate Ti‐Based Metal‐Organic Frameworks
The mixed‐linker series of the titanium‐based metal–organic framework COK‐47 enables systematic tuning of photoresponsiveness and (dark) photocatalytic activity, deepening our understanding of structure‐property‐function relationships. Tailored metal‐to‐ligand charge transfer between the secondary building units (metal‐oxo layers and organic linkers ...
Julia E. Knapp +11 more
wiley +1 more source
Dipole-mediated interfacial solvation for efficient Li-ion transport in dendrite-free Li metal batteries. [PDF]
Zhao W +9 more
europepmc +1 more source
Breaking Bottlenecks in Solid Electrolyte Discovery With Large Artificial Intelligence Models
Large AI models are presented as a route to break key bottlenecks in solid electrolyte discovery by linking materials databases, machine‐learning interatomic potentials, large language models, and autonomous experiments. This perspective highlights how AI can accelerate the identification of solid electrolytes with fast ion transport, stable interfaces,
Eric Jianfeng Cheng +24 more
wiley +1 more source

