Phase Diagrams Enable Solid‐State Battery Design
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
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Electrolyte/electrode interphase regulation with methylthiolation ionic liquids for high-voltage quasi-solid-state Li metal batteries. [PDF]
Li J +8 more
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An intentionally added, chemically formed LixAlSy coating stabilizes the lithium–electrolyte interface in solid‐state Li–S batteries. The layer suppresses side reactions, preserves smooth charge transfer, and improves ion transport from the start. This approach offers a practical route to more durable solid‐state batteries and a clearer understanding ...
Xinyi Wang +4 more
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Three-Dimensional-Printed Polymer-Polymer Composite Electrolytes for All-Solid-State Li Metal Batteries. [PDF]
Wang H, Xiong X, Hu H, Liu S.
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A Family of Sodium Solid‐State Electrolytes Based on the NaGaxAl1‐xCl4 Solid Solution
ABSTRACT Sodium‐based metal chloride solid electrolytes are promising for sodium solid‐state batteries due to their excellent oxidation stability, which, as shown for Li halides, can coexist with high ionic conductivity. To explore cationic substitution effects, we synthesized NaGaxAl1‐xCl4 (0 ≤ x ≤ 1) via ball milling and investigated structural and ...
Hao Guo, Matteo Bianchini
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Taming Interfacial Ion-Dipole Interactions With d-Orbital Delocalized Electron Catalysis Expediates Low-Temperature Li Metal Batteries. [PDF]
Zhang J +16 more
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Graphene layers are fabricated on Cu foil and transferred onto glass substrates to form double‐ and multi‐layer G‐glass. Raman spectroscopy confirms structural integrity, while SEM and fluorescence microscopy reveal favorable adhesion and spreading of L‐929 fibroblast cells.
Mariana Mihaela Apostol +8 more
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Fluorine-free gel polymer electrolyte for lithium oxide-rich solid electrolyte interphase and stable Li metal batteries. [PDF]
Xu W, Zhou L, Lu S, He J, Xu Y, Tian L.
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Life‐Like Ferrous Oxide Microspheres from Kombucha
Kombucha bacterial cellulose, sodium alginate, and ferrous nitrate self‐assemble into membrane‐enclosed iron oxide microspheres. These microspheres bud daughter vesicles, sustain 24‐h electrochemical oscillations, and filter theta‐band signals.
Panagiotis Mougkogiannis +2 more
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Elucidating and Optimizing I Occupation in Lithium Argyrodite Solid Electrolytes for Advanced All-Solid-State Li Metal Batteries. [PDF]
Huang Z +14 more
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