Results 131 to 140 of about 25,653 (262)

Precision Chemistry for Protein Lysine Modification

open access: yesChemistry – A European Journal, EarlyView.
Selective modification of lysine residues is challenging due to their similar intrinsic reactivity. Inspired by enzymatic recognition, ligand‐guided electrophiles enable site‐selective labeling and functionalization, while ligand‐guided catalyses achieve regioselective installation of bio‐relevant post‐translational modifications.
Mayu Onoda, Motomu Kanai
wiley   +1 more source

Rapid Access to Photoswitchable RNA Binders: Fluorination Enhances Protein Rescue by Exon Inclusion

open access: yesChemistry – A European Journal, EarlyView.
An adaptable approach, many light‐switchable RNA binders. We report a versatile strategy for rapidly synthesizing photoswitchable RNA binders. The ligands can target SMN2 pre‐mRNA, restoring the levels of the corresponding protein by exon‐inclusion rescue.
Lei Zhang   +10 more
wiley   +1 more source

Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV

open access: yesChemistry – A European Journal, EarlyView.
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse   +4 more
wiley   +1 more source

Application of Ultrasonic Sensors for Determining the Height of Dynamic Two‐Phase Layers in Tray Columns

open access: yesChemie Ingenieur Technik, EarlyView.
Ultrasonic sensors are evaluated for their applicability in dynamic gas–liquid systems. By comparing sensor data with two independent optical reference methods, their robustness and reliability are demonstrated under varying flow conditions and tray geometries in column systems.
Niklas Breuer   +2 more
wiley   +1 more source

Catalytic Oxidation of CO and VOC in Flue Gas of Coffee Roasting Machines

open access: yesChemie Ingenieur Technik, EarlyView.
Platinum‐coated cordierite monoliths effectively oxidized CO and VOC in coffee roasting exhaust with higher Pt loadings lowering light‐off temperatures. Scaled up 90 g/ft3 catalyst in a 5 kg roaster achieved 96% CO and around 78% VOC conversion at 350°C, highlighting stable operation requires flue gas temperatures ≥350°C.
Till Hauswald   +3 more
wiley   +1 more source

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