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Journal of Chromatography A, 2002
Linear solvation energy relationships allow the prediction of a variety of solubility interactions based on a set of descriptors found in the following equation: [equation: see text]. SP refers to an intrinsic thermodynamic property that can be found experimentally for a series of solutes. Phases containing phosphate, phosphite and phosphine functional
Christine A, Graffis +1 more
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Linear solvation energy relationships allow the prediction of a variety of solubility interactions based on a set of descriptors found in the following equation: [equation: see text]. SP refers to an intrinsic thermodynamic property that can be found experimentally for a series of solutes. Phases containing phosphate, phosphite and phosphine functional
Christine A, Graffis +1 more
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J. Chem. Soc., Faraday Trans. 2, 1981
A new, fundamental linear relationship between the mean energy of a solvated electron and the mean energy of a representative solvent molecule of the system is derived for solvated-electron optical absorption bands which exhibit spectral shape stability.
Sidney Golden, Thomas R. Tuttle
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A new, fundamental linear relationship between the mean energy of a solvated electron and the mean energy of a representative solvent molecule of the system is derived for solvated-electron optical absorption bands which exhibit spectral shape stability.
Sidney Golden, Thomas R. Tuttle
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Chemical Physics Letters, 1982
Abstract The solvatochromic equations describing the effects of solvent polarity/polarizability (π*), solvent hydrogen bond donor acidity (α), and solvent hydrogen bond acceptor basicity (β) have been determined for several thiabendazole homologues.
Patricia C. Tway, L.J. Cline Love
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Abstract The solvatochromic equations describing the effects of solvent polarity/polarizability (π*), solvent hydrogen bond donor acidity (α), and solvent hydrogen bond acceptor basicity (β) have been determined for several thiabendazole homologues.
Patricia C. Tway, L.J. Cline Love
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Linear solvation energy relationships for the hydrogen-bonded complexes of m-cresol
The Journal of Physical Chemistry, 1987Determination par calorimetrie et spectroscopie des energies libres, enthalpies et entropies pour les complexes a liaison H de m-cresol avec diverses bases dans CCl ...
J. N. Spencer +4 more
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Journal of Chromatography A, 1999
Abstract Three olefinic gas chromatographic stationary phases were characterized using a linear solvation energy relationship (LSER) of the type log Vg=c+r1R2+s1πH2+a1ΣαH2+b1ΣβH2+l1log L16, and the results were compared with the LSER coefficients for other, previously characterized, olefinic stationary phases.
Brian K. Callihan +1 more
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Abstract Three olefinic gas chromatographic stationary phases were characterized using a linear solvation energy relationship (LSER) of the type log Vg=c+r1R2+s1πH2+a1ΣαH2+b1ΣβH2+l1log L16, and the results were compared with the LSER coefficients for other, previously characterized, olefinic stationary phases.
Brian K. Callihan +1 more
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Solvatochromic Linear Solvation Energy Relationships for Solubility of O2 in Various Solvents
Bulletin of the Chemical Society of Japan, 1998Abstract Linear solvation energy relationships for solution of O2 in 27 solvents have been examined. Multiple linear regression equations for mole fraction solubility of O2 are developed based on Hildebrand’s solubility parameter as well as the π*, α, and β solvatochromic parameters describing the solvent polarizability/dipolarity ...
Yong Che, Koichi Tokuda, Takeo Ohsaka
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Linear solvation energy relationships: "rule of thumb" for estimation of variable values
Environmental Science & Technology, 1991For the linear solvation energy relationship (LSER), values are listed for each of the variables (V{sub i}/100, {pi}{sup *}, {beta}{sub m}, {alpha}{sub m}) for fundamental organic structures and functional groups. The authors give the guidelines to estimate LSER variable values quickly for a vast array of possible organic compounds such as those found ...
James P. Hickey, Dora R. Passino-Reader
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A New Linear Solvation Energy Relationship for the Solubility of Liquids in Water
Journal of Pharmaceutical Sciences, 1996From a comparison between the linear solvation energy relationship (LSER) and the extended solubility parameter model, it has been found that the solute-solute interaction energy term is missing in the LSER equation. A new LSER equation with the supplementary interaction energy term has been proposed for the solvation process.
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Linear Solvation Energy Relationships for Adsorption of Aromatic Organic Compounds by Microplastics
SSRN Electronic Journal, 2023Dilara Hatinoglu +4 more
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