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Towards practical lithium-metal anodes
Chemical Society Reviews, 2020Lithium ion batteries cannot meet the ever increasing demands of human society. Thus batteries with Li-metal anodes are eyed to revive. Here we summarize the recent progress in developing practical Li-metal anodes for various Li-based batteries.
Xin Zhang, Yongan Yang, Zhen Zhou
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Lithium Host:Advanced architecture components for lithium metal anode
Energy Storage Materials, 2021Abstract With the increasing demand for high energy and power energy storage devices, lithium metal batteries have received widespread attention. Li metal has long been regarded as an ideal candidate for negative electrode due to its high theoretical specific capacity (3860 mAh g−1) and low redox potential (-3.04 V vs.
Yifeng Cheng +6 more
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2021
Deposition and dissolution of lithium metal have been investigated in an equimolar mixture of lithium bis(trifluoromethylsulfonyl)amide (LiTFSA) and glyme [triglyme (G3) or tetraglyme (G4)] solvate ionic liquid. The limiting current for deposition of lithium was not observed probably because of the high concentration of lithium species and a decrease ...
Naoki Tachikawa +2 more
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Deposition and dissolution of lithium metal have been investigated in an equimolar mixture of lithium bis(trifluoromethylsulfonyl)amide (LiTFSA) and glyme [triglyme (G3) or tetraglyme (G4)] solvate ionic liquid. The limiting current for deposition of lithium was not observed probably because of the high concentration of lithium species and a decrease ...
Naoki Tachikawa +2 more
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Angewandte Chemie, 2017
AbstractThe rechargeable lithium metal anode is of utmost importance for high‐energy‐density batteries. Regulating the deposition/dissolution characteristics of Li metal is critical in both fundamental researches and practical applications. In contrast to gray Li deposits featured with dendritic and mossy morphologies, columnar and uniform Li is herein
Xue‐Qiang Zhang +7 more
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AbstractThe rechargeable lithium metal anode is of utmost importance for high‐energy‐density batteries. Regulating the deposition/dissolution characteristics of Li metal is critical in both fundamental researches and practical applications. In contrast to gray Li deposits featured with dendritic and mossy morphologies, columnar and uniform Li is herein
Xue‐Qiang Zhang +7 more
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Lithium Metal Anodes with Nonaqueous Electrolytes
Chemical Reviews, 2020High-energy rechargeable lithium (Li) metal batteries (LMBs) with Li metal anode (LMA) were first developed in the 1970s, but their practical applications have been hindered by the safety and low-efficiency concerns related to LMA. Recently, a worldwide effort on LMA-based rechargeable LMBs has been revived to replace graphite-based, Li-ion batteries ...
Ji-Guang Zhang +4 more
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Carbonlithium anodes for lithium secondary batteries
Journal of Power Sources, 1992Abstract For the development of a superior anode for practical lithium secondary batteries, the carbonlithium composite anode has been studied. As a carbon material, the carbon fiber M46 was mainly studied in this study. This material was proved to be highly reversible in comparison with other carbon materials.
N. Imanishi +5 more
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Lithium anode for lithium-air secondary batteries
Journal of Power Sources, 2008Abstract The lithium ion conducting solid lithium phosphorous nitride (LiPON) has been sputtered on the water-stable NASICON-type lithium ion conducting solid electrolyte Li 1+ x + y Al x Ti 2− x P 3− y Si y O 12 (LATP). The stability and the interface resistance of the Li–Al/LiPON/LATP/LiPON/Li–Al cell have been examined.
Nobuyuki Imanishi +5 more
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Lithium-Anode Protection in Lithium–Sulfur Batteries
Trends in Chemistry, 2019Lithium–sulfur (Li–S) batteries show significant promise as next-generation energy-storage devices due to their high energy density (2600 Wh kg-1). However, the severe shuttling of polysulfide intermediates and low Coulombic efficiency during operation induce rapid capacity loss, hindering their practical applications.
Chong Yan +4 more
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