Results 121 to 130 of about 59,560 (282)

Reactivity of acyclic (pentadienyl)iron(1+) cations: Synthetic studies directed toward the frondosins [PDF]

, 2011
A short, 4-step route to the scaffold of frondosin A and B is reported. The [1-methoxycarbonyl-5-(2′,5′-dimethoxyphenyl)pentadienyl]Fe(CO)3+ cation was prepared in two steps from (methyl 6-oxo-2,4-hexadienoate)Fe(CO)3.
Lee, Do W, Pandey, Rajesh K., Lindeman, Sergey, Donaldson, William   +3 more
core   +1 more source

Light‐Induced Anion Translocation to Control Helical Folding in an Artificial Communication System

Chemistry – A European Journal, EarlyView.
Anion‐induced helical folding of an oligomer is controlled indirectly and reversibly by light through anion uptake/release by a photoresponsive receptor. Thus, a light signal is processed into a chemical signal in a communication‐type three‐component supramolecular system.
Indigo M. Bekaert, Suchismita Saha, Julia Villalva, David Villarón, Maxime A. Siegler, Sander J. Wezenberg   +5 more
wiley   +1 more source

Strain Release of 1‐Azabicyclo[1.1.0]butanes as a Gateway to Highly Functionalized Azetidines: New Strategies and Structural Motifs

Chemistry – A European Journal, EarlyView.
Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato, Philipp Natho, Marco Colella, Renzo Luisi   +3 more
wiley   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque, Niloofar Mozaffari, Louis Fradette, Serge Kaliaguine   +3 more
wiley   +1 more source

Bottlenecks‐Breaking in Zinc‐Iodine Batteries Toward Practical Implementation: A Review and Perspective

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Aqueous zinc–iodine batteries (Zn–I2Bs) offer promise for grid storage due to safety and cost advantages yet face critical bottlenecks: severe self‐discharge (polyiodide shuttling and HER), limited energy density, sluggish kinetics, and zinc anode instability.
Jia‐Lin Yang, Jun‐Ming Cao, Dai‐Huo Liu, Xing‐Long Wu   +3 more
wiley   +1 more source

Chemistry and Biology of Streptogramin A Antibiotics [PDF]

, 2007
The streptogramin A antibiotics have proven to be highly active against Gram positive bacteria, particularly methicillin-resistant Staphylococcus aureus. Members of this group of compounds are characterized by a 23-membered macrocycles containing polyene,
Ahmed, Fahim, Donaldson, William
core   +1 more source

Synergistic‐Induced Perovskite Phase Distribution and Lattice Stabilization for Efficient and Stable Sky‐Blue PeLEDs

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
We have developed a multifunctional buried‐interface engineering strategy using phenethylammonium thiocyanate to regulate quasi‐2D perovskite crystallization and stabilize the lattice. The synergistic effects of SCN− and PEA+ steric confinement promote phase redistribution toward n = 2, suppressing interfacial defects and enabling the production of ...
He Dong, Xiao Qin, Hongyan Chen, Mingrui Lv, Xin Wang, Zhuolin Zhan, Jie Hua, Yuan Chai, Mimi Sun, Jianan Dai, Haipeng Jiang, Jin Wang   +11 more
wiley   +1 more source

Anode/Electrolyte Interfacial Engineering Toward Sustainable and Practical Solid‐State Metal‐Sulfur Batteries: A Prospective Review

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Coordinated engineering of the anode, electrolyte, and interface underpins the rational design of next‐generation solid‐state metal‐sulfur batteries. Solid‐state metal‐sulfur batteries are emerging as a transformative energy storage platform with the potential to overcome the fundamental limitations of conventional flooded cells, particularly ...
Ziyu Feng, Hong Zhang, Peng Wang, Ke Lu, Fei Du   +4 more
wiley   +1 more source

Phenolate‐ and Alcoholate‐Based Chromium N‐Heterocyclic Carbene Complexes: Structural Peculiarities, Magnetometric and Electron Paramagnetic Resonance Study, and Catalytic Ethylene Oligomerization

European Journal of Inorganic Chemistry, EarlyView.
The first low‐oxidation (I/III) state chromium‐complex bearing a O‐chelating NHC ligand has been synthesized and structurally characterized by single‐crystal X‐ray analysis. The formation of the mixed‐valence species was further supported by SQUID magnetometry and high‐field electron paramagnetic resonance (EPR) spectroscopy.
Somnath Bhattacharya, Alexander Allgaier, Wolfgang Frey, Joris van Slageren, Michael R. Buchmeiser   +4 more
wiley   +1 more source

Phosphoryl Halogen and Hydrogen Bonding Controls the Solid‐State Structures of Aryl Halide‐Containing Phosphonates

European Journal of Inorganic Chemistry, EarlyView.
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross, Paweł Horeglad, Bastian Grabe, Wolf Hiller, Vito Lippolis, Massimiliano Arca, Klaus Jurkschat   +6 more
wiley   +1 more source