Interface‐Engineered MXene/g‐C3N4 Heterostructures for Energy and Environmental Applications
This review highlights how interface engineering in MXene/g‐C3N4 heterostructures regulates charge transfer, band alignment, and surface chemistry, enabling broad applications in photocatalytic conversion, environmental remediation, energy storage, and multifunctional sensing/therapy. ABSTRACT Two‐dimensional MXene/g‐C3N4 heterostructures have recently
Feng Wang, Geng Liu, Xiaoqiang An
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We have developed a multifunctional buried‐interface engineering strategy using phenethylammonium thiocyanate to regulate quasi‐2D perovskite crystallization and stabilize the lattice. The synergistic effects of SCN− and PEA+ steric confinement promote phase redistribution toward n = 2, suppressing interfacial defects and enabling the production of ...
He Dong +11 more
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1,3-Brook Rearrangement of α-Silyl Allylic Alcohols: Copper-Catalyzed Enantiospecific Formation of Allenes and Copper-Mediated ipso-Substitution Reactions Affording Trisubstituted Alkenes. [PDF]
A regioselective ruthenium catalyzed trans‐hydrosilylation of propargyl alcohols followed by a 1,3‐Brook rearrangement opens access to reactive organocopper intermediates, which evolve upon warming into allenes with strict chirality transfer to the emerging axis; alternatively, these reactive species can be trapped with a large variety of electrophiles
Sutro JL +3 more
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Coordinated engineering of the anode, electrolyte, and interface underpins the rational design of next‐generation solid‐state metal‐sulfur batteries. Solid‐state metal‐sulfur batteries are emerging as a transformative energy storage platform with the potential to overcome the fundamental limitations of conventional flooded cells, particularly ...
Ziyu Feng +4 more
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As a metalloid with broad prospects in advanced applications, Te has not been fully clarified in terms of its intricate electrochemical behaviors across varied systems. This review systematically integrates fundamental electrochemical mechanisms, reaction kinetics identifications, and device application insights, establishing a comprehensive framework ...
Meng Zhang +6 more
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Ab Initio Molecular Dynamics Simulations of the Influence of Lithium Bromide on the Structure of the Aqueous Solution-Air Interface. [PDF]
Daub CD, Hänninen V, Halonen L.
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Nucleophilic Reactions of Cyclobutenones and the Related 4,4‐Dichlorocyclobutenone Derivatives
Cyclobutenone derivates and their 4,4‐dichloro counterparts have an uninterrupted attention as useful synthons in the synthesis of complex organic molecules. Their nucleophilic reactions remain underexplored. This review brings attention to these reactions, whose outcome is not straightforward.
Sarah J. Wright +2 more
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Ab Initio Molecular Dynamics Simulations of the Influence of Lithium Bromide Salt on the Deprotonation of Formic Acid in Aqueous Solution. [PDF]
Daub CD, Halonen L.
europepmc +1 more source
Solubilities and vapor pressures of the lithium bromide plus calcium nitrate plus water system
Solubilities and vapor pressures of the lithium bromide + calcium nitrate + water system [LiBr/Ca(NO3)(2) mass ratio = 1.0] were measured in various absorbent (lithium bromide + calcium nitrate) concentration and temperature ranges.
Lee, Huen, Kim, JS, Park, Y
core
Navigating the Radical Oxo‐Functionalization of Alkenes Toward Ketones
Straightforward access to complex ketones in a single synthetic step: This Review surveys the latest advances in three‐component alkene 1,2‐oxo‐functionalizations. The opportunities unlocked by the so‐called single‐electron (1e–) logic, including access to a broad pool of radical precursors and carbonyl oxygen atom sources, are highlighted.
Mattia Lepori +3 more
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