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Unity of Opposites between Soluble and Insoluble Lithium Polysulfides in Lithium–Sulfur Batteries
Advanced Materials, 2022AbstractRechargeable batteries based on Li–S chemistry show promise as being possible for next‐generation energy storage devices because of their ultrahigh capacities and energy densities. Research over the past decade has demonstrated that the morphology of lithium polysulfides (LPSs) in electrolytes (soluble or insoluble) plays a decisive role in ...
Chenglin Yan
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Cationic lithium polysulfides in lithium–sulfur batteries
CheM, 2022Yun-Wei Song +11 more
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Advanced Materials
AbstractLithium‐sulfur (Li–S) batteries are widely regarded as one of the most promising next‐generation high‐energy‐density energy storage devices. However, soluble lithium polysulfides (LiPSs) corrode Li metal and deteriorate the cycling stability of Li–S batteries.
Jia-Qi Huang
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AbstractLithium‐sulfur (Li–S) batteries are widely regarded as one of the most promising next‐generation high‐energy‐density energy storage devices. However, soluble lithium polysulfides (LiPSs) corrode Li metal and deteriorate the cycling stability of Li–S batteries.
Jia-Qi Huang
exaly +3 more sources
Heterostructures Regulating Lithium Polysulfides for Advanced Lithium‐Sulfur Batteries
Advanced Materials, 2023AbstractSluggish reaction kinetics and severe shuttling effect of lithium polysulfides seriously hinder the development of lithium‐sulfur batteries. Heterostructures, due to unique properties, have congenital advantages that are difficult to be achieved by single‐component materials in regulating lithium polysulfides by efficient catalysis and strong ...
Tao Wang +6 more
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Nanoscale Horizons, 2020
Introduction of appropriate cathode electrocatalysts in lithium–sulfur or lithium–polysulfide batteries can accelerate the polysulfide interconversion and suppress the shuttle effect.
Yunling Wu +4 more
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Introduction of appropriate cathode electrocatalysts in lithium–sulfur or lithium–polysulfide batteries can accelerate the polysulfide interconversion and suppress the shuttle effect.
Yunling Wu +4 more
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Electrochemistry of a lithium electrode in lithium polysulfide solutions
Russian Journal of Electrochemistry, 2008The effect of lithium polysulfides on the cycling of a lithium electrode and the corrosion rate of lithium cathodic deposits in sulfolane electrolytes is studied. Lithium polysulfides are found to affect the shape of polarization curves, the overpotential of electrode processes, and the cycling time.
V. S. Kolosnitsyn +2 more
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Self‐Assembled Networks for Regulating Lithium Polysulfides in Lithium‐Sulfur Batteries
ChemSusChem, 2022AbstractInhibiting the shuttle effect caused by soluble lithium polysulfides (LiPSs) is of importance for lithium‐sulfur (Li−S) batteries. Here, a strategy was developed to construct protective layers by self‐assembly networks to regulate the LiPSs. 2,5‐Dichloropyridine (25DCP) holds two kinds of functional groups.
Zhihua Wang +5 more
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Physical Chemistry Chemical Physics, 2021
The discharge voltage of reactions for formation of Li2Sn from S8 is higher than that for formation of Li2S from Li2Sn.
Seiji Tsuzuki +8 more
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The discharge voltage of reactions for formation of Li2Sn from S8 is higher than that for formation of Li2S from Li2Sn.
Seiji Tsuzuki +8 more
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Design considerations for lithium–sulfur batteries: mass transport of lithium polysulfides
Nanoscale, 2020The mass transport of soluble LiPSs is a significant important factor determining the performance of sulfur cathode. The effect of mass transport was clearly elucidated.
Seong-Jun Kim +4 more
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Chemical Immobilization Effect on Lithium Polysulfides for Lithium–Sulfur Batteries
Small, 2017AbstractDespite great progress in lithium–sulfur batteries (LSBs), great obstacles still exist to achieve high loading content of sulfur and avoid the loss of active materials due to the dissolution of the intermediate polysulfide products in the electrolyte.
Caixia Li +4 more
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