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Unity of Opposites between Soluble and Insoluble Lithium Polysulfides in Lithium–Sulfur Batteries

Advanced Materials, 2022
AbstractRechargeable batteries based on Li–S chemistry show promise as being possible for next‐generation energy storage devices because of their ultrahigh capacities and energy densities. Research over the past decade has demonstrated that the morphology of lithium polysulfides (LPSs) in electrolytes (soluble or insoluble) plays a decisive role in ...
Chenglin Yan
exaly   +3 more sources

Cationic lithium polysulfides in lithium–sulfur batteries

CheM, 2022
Yun-Wei Song   +11 more
exaly   +2 more sources

Unveiling the Reaction Mystery Between Lithium Polysulfides and Lithium Metal Anode in Lithium–Sulfur Batteries

Advanced Materials
AbstractLithium‐sulfur (Li–S) batteries are widely regarded as one of the most promising next‐generation high‐energy‐density energy storage devices. However, soluble lithium polysulfides (LiPSs) corrode Li metal and deteriorate the cycling stability of Li–S batteries.
Jia-Qi Huang
exaly   +3 more sources

Heterostructures Regulating Lithium Polysulfides for Advanced Lithium‐Sulfur Batteries

Advanced Materials, 2023
AbstractSluggish reaction kinetics and severe shuttling effect of lithium polysulfides seriously hinder the development of lithium‐sulfur batteries. Heterostructures, due to unique properties, have congenital advantages that are difficult to be achieved by single‐component materials in regulating lithium polysulfides by efficient catalysis and strong ...
Tao Wang   +6 more
openaire   +2 more sources

Molybdenum carbide nanostructures for electrocatalytic polysulfide conversion in lithium–polysulfide batteries

Nanoscale Horizons, 2020
Introduction of appropriate cathode electrocatalysts in lithium–sulfur or lithium–polysulfide batteries can accelerate the polysulfide interconversion and suppress the shuttle effect.
Yunling Wu   +4 more
openaire   +2 more sources

Electrochemistry of a lithium electrode in lithium polysulfide solutions

Russian Journal of Electrochemistry, 2008
The effect of lithium polysulfides on the cycling of a lithium electrode and the corrosion rate of lithium cathodic deposits in sulfolane electrolytes is studied. Lithium polysulfides are found to affect the shape of polarization curves, the overpotential of electrode processes, and the cycling time.
V. S. Kolosnitsyn   +2 more
openaire   +1 more source

Self‐Assembled Networks for Regulating Lithium Polysulfides in Lithium‐Sulfur Batteries

ChemSusChem, 2022
AbstractInhibiting the shuttle effect caused by soluble lithium polysulfides (LiPSs) is of importance for lithium‐sulfur (Li−S) batteries. Here, a strategy was developed to construct protective layers by self‐assembly networks to regulate the LiPSs. 2,5‐Dichloropyridine (25DCP) holds two kinds of functional groups.
Zhihua Wang   +5 more
openaire   +2 more sources

Thermodynamic aspect of sulfur, polysulfide anion and lithium polysulfide: plausible reaction path during discharge of lithium–sulfur battery

Physical Chemistry Chemical Physics, 2021
The discharge voltage of reactions for formation of Li2Sn from S8 is higher than that for formation of Li2S from Li2Sn.
Seiji Tsuzuki   +8 more
openaire   +2 more sources

Design considerations for lithium–sulfur batteries: mass transport of lithium polysulfides

Nanoscale, 2020
The mass transport of soluble LiPSs is a significant important factor determining the performance of sulfur cathode. The effect of mass transport was clearly elucidated.
Seong-Jun Kim   +4 more
openaire   +2 more sources

Chemical Immobilization Effect on Lithium Polysulfides for Lithium–Sulfur Batteries

Small, 2017
AbstractDespite great progress in lithium–sulfur batteries (LSBs), great obstacles still exist to achieve high loading content of sulfur and avoid the loss of active materials due to the dissolution of the intermediate polysulfide products in the electrolyte.
Caixia Li   +4 more
openaire   +2 more sources

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