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Formation of lithium polysulfides in aprotic media

Journal of Inorganic and Nuclear Chemistry, 1977
Abstract The formation of Li 2 S n in certain aprotic media can be accomplished either by electrochemical reduction of S 8 or by direct in situ reaction of S 8 with Li or Li 2 S. Polysulfide solubilities and spectra vary widely in different solvents as a result of solvent-solute interactions. A requirement for high polysulfide concentration is
R.D. Rauh   +3 more
openaire   +1 more source

A Core-Shell structured Sulfur Cathode: Ultrathin δ-MnO2 Nanosheets as Catalytic Conversion Shell for Lithium Polysulfides in High-Sulfur Content Lithium-Sulfur Batteries.

ACS Applied Materials and Interfaces, 2020
Owing to their low cost and high theoretical energy density, lithium-sulfur (Li-S) batteries are highly promising as a contender for post-lithium ion battery era.
Qing Li   +6 more
semanticscholar   +1 more source

Dissociation-Precipitation Chemistry of Lithium Polysulfides and Its Correlation to Dynamic Evolution of Cathode-Electrolyte Interphase in Highly Solvating Electrolyte.

Angewandte Chemie
Lithium-sulfur (Li-S) batteries has been regarded as one of the most promising next-generation energy storage systems due to their high theoretical energy density.
Luyi Chen   +8 more
semanticscholar   +1 more source

Grafting and Depositing Lithium Polysulfides on Cathodes for Cycling Stability of Lithium–Sulfur Batteries

ACS Applied Materials & Interfaces, 2021
Based on dissolution/deposition chemistry, together with multielectron redox reactions, lithium-sulfur (Li-S) batteries have been demonstrated as a promising energy storage system. However, the diffusion of soluble lithium polysulfide intermediates (LiPSs) to bulk electrolyte results in the fast capacity fade of a Li-S cell.
Junfeng Wu   +5 more
openaire   +2 more sources

Effect of Lithium Polysulfide As Electrolyte Additive in Lithium Sulfur Batteries

ECS Meeting Abstracts, 2014
Recently, the lithium–sulfur battery is considered as a high-energy-density storage and power device for sustainable electric vehicles (EVs) due to its high theoretical energy density and natural abundanc.1 However, there are some drawbacks to introduce this battery into commercial devices.
D. J. Lee   +7 more
openaire   +3 more sources

Shuttle confinement of lithium polysulfides in borocarbonitride nanotubes with enhanced performance for lithium–sulfur batteries

Journal of Materials Chemistry A, 2020
Borocarbonitride nanotubes show efficient physical and chemical anchoring and conversion of lithium polysulfides, ensuring the enhanced electrochemical performance in lithium–sulfur batteries.
Mingzhi Yang   +8 more
semanticscholar   +1 more source

Kinetics of Lithium-Polysulfide Flow Batteries

ECS Meeting Abstracts, 2014
We recently demonstrated that the high solubility of polysulfides in nonaqueous electrolytes can be exploited to make a high energy density lithium-sulfur flow battery with low storage cost1–3. Here we used a new approach, whereby percolating networks of nanoscale conductor particles (in this case carbon black) are incorporated within the electrode ...
Frank Fan   +6 more
openaire   +1 more source

A Multifunctional Layered Ti3C2Tx/VS2 Composite Sulfur Host for Promoting the Conversion of Lithium Polysulfides in Lithium-Sulfur Batteries

Journal of Materials Chemistry A
Lithium-sulfur (Li-S) batteries show promise in meeting the requirements for high energy density and cost-effective energy storage system.
Guisheng Deng   +8 more
semanticscholar   +1 more source

Cooperative Catalysis of Polysulfides in Lithium-Sulfur Batteries through Adsorption Competition by Tuning Cationic Geometric Configuration of Dual-active Sites in Spinel Oxides.

Angewandte Chemie, 2022
Fundamentally understanding the structure-property relationship is critical to design advanced electrocatalysts for lithium-sulfur (Li-S) batteries, which remains a formidable challenge.
Hongtai Li   +9 more
semanticscholar   +1 more source

Chemical Confinement and Utility of Lithium Polysulfides in Lithium Sulfur Batteries

Small Methods, 2019
AbstractLithium sulfur (Li–S) batteries featuring abundant resources and cost‐efficiency are regarded as a promising next‐generation energy storage system with high theoretical capacity and energy density. However, several drawbacks impede the development of Li–S batteries, especially the shuttle effects of soluble lithium polysulfides (LiPS) which ...
Tianyu Tang, Yanglong Hou
openaire   +1 more source

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