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In Situ Polysulfide Detection in Lithium Sulfur Cells

The Journal of Physical Chemistry Letters, 2018
Lithium sulfur batteries promise significant improvements in specific energy compared to Li-ion, but are limited by capacity fade upon cycling. Efforts to improve durability have focused on suppressing the solubility of intermediate polysulfides in the electrolyte.
John-Paul Jones   +4 more
openaire   +2 more sources

Poly(ionic liquid) Based Quasi-Solid-State Copolymer Electrolytes for Dynamic-Reversible Adsorption of Lithium Polysulfides in Lithium-Sulfur Batteries.

ACS Applied Materials and Interfaces, 2019
The shuttle of the intermediate lithium polysulfides (LiPSs) is the main obstacle to the practical application of lithium-sulfur batteries. Herein, a poly(butyl acrylate/1-ethyl-3-vinylimidazole bis[(trifluoromethyl)sulfonyl]imide) based quasi-solid ...
Xiaomin Cai   +5 more
semanticscholar   +1 more source

Carbon Nitride Phosphorus as an Effective Lithium Polysulfide Adsorbent for Lithium–Sulfur Batteries

ACS Applied Materials & Interfaces, 2019
Lithium-sulfur (Li-S) batteries are attracting substantial attention because of their high-energy densities and potential applications in portable electronics. However, an intrinsic property of Li-S systems, that is, the solubility of lithium polysulfides (LiPSs), hinders the commercialization of Li-S batteries.
Vandung Do   +5 more
openaire   +2 more sources

Sulfur-deficient MoS2-x promoted lithium polysulfides conversion in lithium-sulfur battery: A first-principles study

Applications of Surface Science, 2019
The lithium‑sulfur batteries are becoming the promising next generation large-scale electrical energy storage, due to the high specific energy density and theoretical capacity.
Qi Zhang   +4 more
semanticscholar   +1 more source

Hybrid Lithium–Sulfur Batteries with a Solid Electrolyte Membrane and Lithium Polysulfide Catholyte

ACS Applied Materials & Interfaces, 2015
Lithium-sulfur (Li-S) batteries are receiving great attention as the most promising next-generation power source with significantly high charge-storage capacity. However, the implementation of Li-S batteries is hampered by a critical challenge because of the soluble nature of the intermediate polysulfide species in the liquid electrolyte.
Xingwen, Yu   +3 more
openaire   +2 more sources

Stabilized Lithium–Metal Surface in a Polysulfide-Rich Environment of Lithium–Sulfur Batteries

The Journal of Physical Chemistry Letters, 2014
Lithium-metal anode degradation is one of the major challenges of lithium-sulfur (Li-S) batteries, hindering their practical utility as next-generation rechargeable battery chemistry. The polysulfide migration and shuttling associated with Li-S batteries can induce heterogeneities of the lithium-metal surface because it causes passivation by bulk ...
Chenxi, Zu, Arumugam, Manthiram
openaire   +2 more sources

The Relationship between the Relative Solvating Power of Electrolytes and Shuttling Effect of Lithium Polysulfides in Lithium-Sulfur Batteries.

Angewandte Chemie, 2018
Relative solvating power, that is, the ratio of the coordination ratios between a solvent and the reference solvent, was used to probe the quantitative structure-activity relationship of electrolyte solvents and the lithium polysulfide (LiPS) dissolution
Chi‐Cheung Su   +4 more
semanticscholar   +1 more source

High-power lithium polysulfide-carbon battery

Carbon, 2016
Abstract We report a lithium battery using activated carbon on gas diffusion layer (GDL) electrode as host for lithium polysulfide conversion reaction. The cell operates within 2.8 and 2.1 V and delivers a capacity ranging from 400 mAh g −1 at 1C to 150 mAh g −1 at 40C over 100 cycles.
Shin H. -D.   +4 more
openaire   +2 more sources

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