Results 81 to 90 of about 253,426 (203)

Synergetic Interlayer in Li‐S Batteries: Polysulfide‐Impeding Effect of Conductive Carbon Cloth Supporting Topological‐Phase Bi2Se3

open access: yesChemElectroChem
The shuttle effect and sluggish sulfur conversion kinetics hamper the development of lithium–sulfur batteries. In this study, Bi2Se3 nanosheets were grown in‐situ directly on a carbon cloth and adopted as an interlayer in lithium–sulfur batteries to ...
Heng Wang   +5 more
doaj   +1 more source

A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium–sulfur batteries

open access: yesNature Communications, 2016
The promise of lithium-sulfur batteries with higher energy densities than lithium-ion is hindered by the insulating nature of sulfur and dissolution of polysulfides.
Zhen Li   +5 more
doaj   +1 more source

Improving lithium polysulfides redox with spinel oxides for lithium-sulfur batteries

open access: yes, 2020
Lithium-sulfur (Li-S) batteries have been recognized as potential candidates for next-generation rechargeable cells because of their high energy density.
Shen, Chen
core  

2D MoN‐VN Heterostructure To Regulate Polysulfides for Highly Efficient Lithium‐Sulfur Batteries

open access: yes, 2018
Lithium-sulfur batteries hold promise for next-generation batteries. A problem however is rapid capacity fading. Moreover, atomic-level understanding of the chemical interaction between sulfur host and polysulfides is poorly elucidated from a theoretical
Yan Jiao   +13 more
core   +1 more source

Internal Electric Field‐Guided, Low‐Adsorption Ferroelectric Anode Protective Layers for Sustainable Suppression of Polysulfide Side Reactions in Lithium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A positively polarized ferroelectric β‐pvdf layer incorporating fluorinated boron nitride nanosheets (PPFBN) establishes a strong internal field that promotes Li+ transport toward the anode while suppressing the migration of polysulfide anions. In addition, its intrinsically low polysulfide affinity helps preserve protective‐layer functionality ...
Daehun Han   +6 more
wiley   +1 more source

Multi‐modal Operando Analysis of Lithium–Sulfur Batteries: A Comparative Study on the Influence of Electrolyte Composition

open access: yesAdvanced Energy Materials, EarlyView.
The influence of different electrolytes on Lithium–sulfur batteries is investigated. Multimodal operando analysis, including Raman, UV–vis, and Impedance spectroscopy is used to study degradation mechanisms. The solubility of polysulfides in the electrolyte is crucial for battery capacity and lifetime.
Oliver Löhmann   +3 more
wiley   +1 more source

An ultrathin and crack‐free metal‐organic framework film for effective polysulfide inhibition in lithium–sulfur batteries

open access: yesInterdisciplinary Materials
Due to their extensive microporous structure, metal‐organic frameworks (MOFs) find widespread application in constructing modification layers, functioning as ion sieves.
Cheng Zhou   +7 more
doaj   +1 more source

Porous Carbon Interlayer Derived from Traditional Korean Paper for Li–S Batteries

open access: yesNanomaterials
A carbonized interlayer effectively helps to improve the electrochemical performance of lithium–sulfur (Li–S) batteries. In this study, a simple and inexpensive carbon intermediate layer was fabricated using a traditional Korean paper called “hanji ...
Yunju Choi   +6 more
doaj   +1 more source

Decoupling Quasi‐Solid‐State Sulfur Conversion Mechanisms in Weakly Solvating and Locally High Concentration Electrolytes

open access: yesAdvanced Energy Materials, EarlyView.
Weakly solvating CME–TTE and localized high‐concentration G2–TTE electrolytes redirect lithium–sulfur chemistry toward quasi‐solid‐state conversion through distinct coordination environments. Molecular dynamics and multimodal electrochemical and spectroscopic measurements show that G2–TTE couples multidentate solvent coordination, anion participation ...
Boyi Pang   +12 more
wiley   +1 more source

Polysulfides Capture-Copper Additive for Long Cycle Life Lithium Sulfur Batteries

open access: yes, 2016
Copper powder was introduced into the lithium sulfur battery system to capture intermediate polysulfides and CuxS (x = 1 or 2) species was generated depending on the chain length of polysulfides. This phenomenon was verified by X-ray absorption near edge
Wentao Zhu (477548)   +5 more
core   +1 more source

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