Results 61 to 70 of about 451,954 (260)

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

Angewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang, Youfu Wang, Xinyuan Zhu, Jinhong Jia, Xiaofeng Wu, Tom Hasell   +5 more
wiley   +2 more sources

β-FeOOH Interlayer With Abundant Oxygen Vacancy Toward Boosting Catalytic Effect for Lithium Sulfur Batteries

Frontiers in Chemistry, 2020
Due to the shuttle effect and low conductivity of sulfur (S), it has been challenging to realize the application of lithium-sulfur (Li-S) batteries with high performance and long cyclability. In this study, a high catalytic active CNTs@FeOOH composite is
Yingying Li, Xifei Li, Xifei Li, Xifei Li, Youchen Hao, Alibek Kakimov, Dejun Li, Qian Sun, Liang Kou, Zhanyuan Tian, Le Shao, Cheng Zhang, Jiujun Zhang, Jiujun Zhang, Xueliang Sun, Xueliang Sun, Xueliang Sun   +16 more
doaj   +1 more source

Interfacial Polysulfide Confinement via Spatially Controlled Sulfonated Metal–Organic Polyhedra Coatings in Lithium–Sulfur Batteries

Advanced Science, EarlyView.
Spatially controlled sulfonated metal–organic polyhedra (SMOP) coating on sulfur‐loaded hollow carbon spheres form ultrathin, conformal interfacial barriers that selectively confine soluble polysulfides, stabilize sulfur redox, and suppress shuttle reactions.
Soyeon Ko, WooYeon Moon, Yuwei Zhu, Yuhui An, Yunyuan Lu, Sourayan Bal, Linqin Mu, Kyung Min Choi, Yoon Hwa   +8 more
wiley   +1 more source

Versatile Asymmetric Separator with Dendrite‐Free Alloy Anode Enables High‐Performance Li–S Batteries

Advanced Science, 2022
Lithium–sulfur batteries (LSBs) with extremely‐high theoretical energy density (2600 Wh kg−1) are deemed to be the most likely energy storage system to be commercialized.
Wenqi Yan, Jin‐Lin Yang, Xiaosong Xiong, Lijun Fu, Yuhui Chen, Zhaogen Wang, Yusong Zhu, Jian‐Wei Zhao, Tao Wang, Yuping Wu   +9 more
doaj   +1 more source

Enhancing Li‐S Battery Performance Through Low‐Concentration Electrolytes with Organic Se/Te Co‐Additives to Address Solubility and Kinetic Challenges

Advanced Science, EarlyView.
This work presents a low‐concentration electrolyte enabled by hybrid organic Se/Te additives (DPDSe/DPDTe) that restructures solvation, boosts polysulfide dissolution, and provides dual‐site synergistic catalysis, delivering high capacity and stable cycling in Li–S coin and pouch cells, supporting high‐energy, high‐power operation.
Ruihua Li, Haiwei Wu, Hairu Wei, Wenhao Jia, Frederik Bettels, Leon Schenk, Zhihua Lin, Hanbin Liu, Guodong Liu, Zhijian Li, Lin Zhang   +10 more
wiley   +1 more source

A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium–sulfur batteries

Nature Communications, 2016
The promise of lithium-sulfur batteries with higher energy densities than lithium-ion is hindered by the insulating nature of sulfur and dissolution of polysulfides.
Zhen Li, Jintao Zhang, Buyuan Guan, Da Wang, Li-Min Liu, Xiong Wen (David) Lou   +5 more
doaj   +1 more source

Development of high-energy non-aqueous lithium-sulfur batteries via redox-active interlayer strategy

Nature Communications, 2022
Lithium-sulfur batteries promise high energy density, but polysulfide shuttling acts as a major stumbling block toward practical development. Here, a redox-active interlayer is proposed to confine polysulfides, increase the cell capacity and improve cell
Byong-June Lee, Chen Zhao, Jeong-Hoon Yu, Tong-Hyun Kang, Hyean-Yeol Park, Joonhee Kang, Yongju Jung, Xiang Liu, Tianyi Li, Wenqian Xu, Xiao-Bing Zuo, Gui-Liang Xu, Khalil Amine, Jong-Sung Yu   +13 more
doaj   +1 more source

Deciphering the Dynamic Balance Between Solvation Strength and Polysulfides Reaction Heterogeneity in Practical Lithium‐Sulfur Batteries

Advanced Science, EarlyView.
A weakly solvating fluorinated cosolvent (1200ET) enables precise solvation‐power regulation in Li–S batteries, decoupling interfacial stabilization from sulfur redox kinetics. This approach suppresses polysulfide dissolution while preserving reaction kinetics, leading to a stable Li metal interface and high‐energy multilayer pouch cells, revealing a ...
Huidong Dai, Pranathi Garlapati, Srinidi Badhrinathan, Luisa Gomes, Tongtai Ji, Dominik Wierzbicki, Yonghua Du, Neville Pavri, Sanjeev Mukerjee, Gaind P. Pandey   +9 more
wiley   +1 more source

Fast polysulfides conversion and regulated lithium plating enabled by W2N quantum dots for high‐performance lithium sulfur batteries

EcoEnergy
Lithium sulfur (Li‐S) batteries have been regarded as one of the most promising next‐generation batteries. However, the shuttle effect caused by solubility and sluggish kinetics of polysulfides on the cathode and the uneven deposition of lithium on the ...
Linfeng He, Zhuyu Luo, Ping Liu, Xin Zhu, Wenbo Fan, Qi Yu, Xiaoyan Liu, Hexing Li   +7 more
doaj   +1 more source

Beyond d‐Band Catalysis: A Critical Review and Descriptor Framework for Rare‐Earth Engineering in Lithium–Sulfur Batteries

Advanced Science, EarlyView.
Rare‐earth catalysts regulate lithium–sulfur battery chemistry through f‐orbital–mediated interactions, enabling simultaneous polysulfide adsorption and catalytic conversion on conductive carbon hosts. This synergistic control suppresses the shuttle effect, accelerates redox kinetics, and guides stable Li2S nucleation, providing a mechanistic framework
Fan Wang, Shihzad Shakil, Guozhi Wu, Jiarui Huang, Hanhui Lei, Terence Xiaoteng Liu   +5 more
wiley   +1 more source