Quasi-Living Polymerization of Propene with an Isotactic-Specific Zirconocene Catalyst [PDF]
Molecules, 2017 Propene polymerization with isotactic (iso)-specific C2-symmetric rac-Me2Si(2-Me-Benz(e)-Ind)2ZrCl2 (1) and rac-Me2Si(2-Me-4-Ph-1-Ind)2ZrCl2 (2) were conducted under various conditions for achieving iso-specific living polymerization of propene.
Kei Nishii +2 more
doaj +2 more sources
Photo-excited extracellular electron transfer of electroactive microorganism triggers RAFT polymerization [PDF]
Nature CommunicationsLiving cell-triggered reversible addition-fragmentation chain-transfer (RAFT) polymerization is of great value for construction of living materials with diverse applications.
Chao Li +13 more
doaj +2 more sources
Living Cationic Polymerization of Silyl-Protected β-Methyl Vinyl Ethers (Propenyl Ethers): Synthesis of Hydroxy-Functional Polymers with High Tg and LCST-Type Thermoresponse [PDF]
MoleculesHydroxy-functional poly(propenyl ether)s are promising thermoresponsive materials; here we establish a controlled synthesis via living cationic polymerization of silyl-protected monomers.
Kohei Watanabe +2 more
doaj +2 more sources
Photoinduced Controlled/Living Polymerizations
Angewandte Chemie International Edition, 2022 AbstractThe application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low‐energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings,
Cansu Aydogan +4 more
openaire +3 more sources
Visible light-controlled living cationic polymerization of methoxystyrene
Nature Communications, 2022 Photo-controlled living polymerization has received great attention in recent years but the reports on photo-controlled living cationic polymerization are limited.
Lei Wang +9 more
doaj +1 more source
Application of Polymeric Nanocomposites Prepared via Reversible Addition-Fragmentation Chain-Transfer (RAFT) Polymerization in Drug Delivery: A Brief Review [PDF]
Baspārish, 2022 Recently, the use of controlled-radical polymerization methods for the preparation of various polymer materials has received much attention due to the advantages of these methods and the elimination of the disadvantages of radical polymerization.
Ali Pourjavadi +2 more
doaj +1 more source
Nanocompartment-confined polymerization in living systems
Nature Communications, 2023 Polymerization in living systems has become an effective strategy to regulate cell functions and behavior. However, the requirement of high concentrations of monomers, the existence of complicated intracorporal interferences, and the demand for extra ...
Yun Chen +9 more
doaj +1 more source
Macromol, 2021 The cationic polymerization of isobutylene and its block copolymerization with styrene using DiCumCl/TiCl4/2,6-lutidine initiating system has been studied in open conditions.
Miraslau I. Makarevich +8 more
doaj +1 more source
Living supramolecular polymerization of fluorinated cyclohexanes
Nature Communications, 2021 Living supramolecular polymerization can produce precise covalent polymers, but the scope of monomers is still narrow. Here the authors show a molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1 ...
Oleksandr Shyshov +8 more
doaj +1 more source
Advanced NanoBiomed Research, 2023 The cellular environment offers some unique features to carry out polymerizations under controlled conditions. Polymerization of monomers in cellular compartments and on the surface of living organisms holds much promise in the engineering of ...
Partha Laskar +2 more
doaj +1 more source