Results 11 to 20 of about 42,028 (156)

Stereospecific cationic RAFT polymerization of bulky vinyl ethers and stereoblock poly(vinyl alcohol) via mechanistic transformation to radical RAFT polymerization of vinyl acetate

open access: yesGiant, 2021
The simultaneous control of molecular weight and tacticity in cationic polymerization remains challenging. Here, we propose a new approach for stereospecific living cationic polymerization by combining cationic reversible addition-fragmentation chain ...
Mineto Uchiyama   +2 more
doaj   +1 more source

Block Copolymer Synthesis by the Combination of Living Cationic Polymerization and Other Polymerization Methods

open access: yesFrontiers in Chemistry, 2021
The foremost limitation of block copolymer synthesis is to polymerize two or more different types of monomers with different reactivity profiles using a single polymerization technique. Controlled living polymerization techniques play a vital role in the
Asmita Dey, Ujjal Haldar, Priyadarsi De
doaj   +1 more source

Hierarchical Self-Assembled Structures from Diblock Copolymer Mixtures by Competitive Hydrogen Bonding Strength

open access: yesMolecules, 2018
In this work we prepared poly(styrene–b–vinylphenol) (PS-b-PVPh) by sequential anionic living polymerization and poly(ethylene oxide-b-4-vinylpyridine) (PEO-b-P4VP) by reversible addition fragmentation chain transfer polymerization (RAFT) by ...
Tzu-Chun Tseng, Shiao-Wei Kuo
doaj   +1 more source

Tyrosine residues initiated photopolymerization in living organisms

open access: yesNature Communications, 2023
Towards intracellular engineering of living organisms, the development of new biocompatible polymerization system applicable for an intrinsically non-natural macromolecules synthesis for modulating living organism function/behavior is a key step. Herein,
Mei Zhu   +6 more
doaj   +1 more source

Living Radical Polymerization 4. Stereospecific Living Radical Polymerization

open access: yesInternational Polymer Science and Technology, 2010
Living radical polymerization (LRP) enables the control of molecular weight and molecular weight distribution of polymers synthesized, but it is no effect on stereoregulation (tacticity) of the polymer. With the progress of stereospecific radical polymerizations, several attempts have been made to combine it with LRP to achieve simultaneous control of ...
Shigeru YAMAGO, Yasuyuki NAKAMURA
openaire   +2 more sources

Recent Developments in C–H Activation for Materials Science in the Center for Selective C–H Activation

open access: yesMolecules, 2018
Organic electronics is a rapidly growing field driven in large part by the synthesis of π-conjugated molecules and polymers. Traditional aryl cross-coupling reactions such as the Stille and Suzuki have been used extensively in the synthesis of &pi ...
Junxiang Zhang   +5 more
doaj   +1 more source

Automation of Controlled/Living Radical Polymerization

open access: yesAdvanced Intelligent Systems, 2020
Controlled/living radical polymerization (CLRP) techniques are widely utilized to synthesize advanced and controlled synthetic polymers for chemical and biological applications.
Matthew Tamasi   +4 more
doaj   +1 more source

Preparation of Polyacrylamide with Improved Tacticity and Low Molecular Weight Distribution [PDF]

open access: yesBIO Web of Conferences, 2022
Polyacrylamide with improved tacticity and low molecular weight distribution was obtained via stereospecific atom transfer radical polymerization (ATRP) using the mixture of Lewis acids Y(OTf)3 and AlCl3 in a certain ratio as stereospecific catalyst and ...
Jiang Jianguo   +4 more
doaj   +1 more source

Synthesis of Poly(norbornene-methylamine), a Biomimetic of Chitosan, by Ring-Opening Metathesis Polymerization (ROMP)

open access: yesMarine Drugs, 2017
ROMP is an effective method for preparing functional polymers due to its having characteristics of “living” polymerization and rapid development of catalysts.
Na Li   +3 more
doaj   +1 more source

Study of Atom Transfer Radical Polymerization of Styrene and Its Gel Effect by Monte Carlo Simulation Method [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2009
Atom transfer radical polymerization (ATRP) of styrene was carried out at 105°C and a Monte Carlo simulation was employed to model the system. The variations of monomer conversion, the initiator concentration, average molecular weight, and molecular ...
M. Najafi   +3 more
doaj   +1 more source

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