Results 11 to 20 of about 42,028 (156)
The simultaneous control of molecular weight and tacticity in cationic polymerization remains challenging. Here, we propose a new approach for stereospecific living cationic polymerization by combining cationic reversible addition-fragmentation chain ...
Mineto Uchiyama +2 more
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The foremost limitation of block copolymer synthesis is to polymerize two or more different types of monomers with different reactivity profiles using a single polymerization technique. Controlled living polymerization techniques play a vital role in the
Asmita Dey, Ujjal Haldar, Priyadarsi De
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In this work we prepared poly(styrene–b–vinylphenol) (PS-b-PVPh) by sequential anionic living polymerization and poly(ethylene oxide-b-4-vinylpyridine) (PEO-b-P4VP) by reversible addition fragmentation chain transfer polymerization (RAFT) by ...
Tzu-Chun Tseng, Shiao-Wei Kuo
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Tyrosine residues initiated photopolymerization in living organisms
Towards intracellular engineering of living organisms, the development of new biocompatible polymerization system applicable for an intrinsically non-natural macromolecules synthesis for modulating living organism function/behavior is a key step. Herein,
Mei Zhu +6 more
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Living Radical Polymerization 4. Stereospecific Living Radical Polymerization
Living radical polymerization (LRP) enables the control of molecular weight and molecular weight distribution of polymers synthesized, but it is no effect on stereoregulation (tacticity) of the polymer. With the progress of stereospecific radical polymerizations, several attempts have been made to combine it with LRP to achieve simultaneous control of ...
Shigeru YAMAGO, Yasuyuki NAKAMURA
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Organic electronics is a rapidly growing field driven in large part by the synthesis of π-conjugated molecules and polymers. Traditional aryl cross-coupling reactions such as the Stille and Suzuki have been used extensively in the synthesis of &pi ...
Junxiang Zhang +5 more
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Automation of Controlled/Living Radical Polymerization
Controlled/living radical polymerization (CLRP) techniques are widely utilized to synthesize advanced and controlled synthetic polymers for chemical and biological applications.
Matthew Tamasi +4 more
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Preparation of Polyacrylamide with Improved Tacticity and Low Molecular Weight Distribution [PDF]
Polyacrylamide with improved tacticity and low molecular weight distribution was obtained via stereospecific atom transfer radical polymerization (ATRP) using the mixture of Lewis acids Y(OTf)3 and AlCl3 in a certain ratio as stereospecific catalyst and ...
Jiang Jianguo +4 more
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ROMP is an effective method for preparing functional polymers due to its having characteristics of “living” polymerization and rapid development of catalysts.
Na Li +3 more
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Study of Atom Transfer Radical Polymerization of Styrene and Its Gel Effect by Monte Carlo Simulation Method [PDF]
Atom transfer radical polymerization (ATRP) of styrene was carried out at 105°C and a Monte Carlo simulation was employed to model the system. The variations of monomer conversion, the initiator concentration, average molecular weight, and molecular ...
M. Najafi +3 more
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