Results 121 to 130 of about 16,371 (260)

Deciphering Polarity Effects of Polymer to Regulate Li+ Ionic Environment in Solid Polymer Electrolytes for Solid‐State Lithium Batteries

open access: yesCarbon Energy, EarlyView.
We elucidate the fundamental influences of polymer polarity on Li+ ionic environments in solid polymer electrolytes by considering four critical components: Li+, FSI−, residual solvents, and polymer matrix. Beyond facilitating LiFSI dissociation and Li+ transport, our findings underscore previously overlooked roles of polymer polarity, thereby ...
Ji‐Oh Kim   +7 more
wiley   +1 more source

Substituent‐Dependent SERS Kinetics of Citrate‐Stabilized Gold Nanoparticles: Balancing Hotspot Formation and Colloidal Flocculation

open access: yesChemistry – A European Journal, EarlyView.
Reporter chemistry controls the operational window of liquid‐phase SERS. Para‐substituted benzenethiols induce distinct AuNPs colloidal regimes, ranging from delayed but stable hotspot formation to rapid flocculation‐dominated signal decay. The balance between SERS‐active‐state formation and colloidal loss defines whether a reporter provides reliable ...
Irene Calderon Gonzalez   +2 more
wiley   +1 more source

From Charge‐Transfer Adducts to (Tri)Halide‐Templated Supramolecular Cages: Covalent vs Ionic Products in the Reactions of Pyridin‐4‐ylthio‐Substituted Tetrathiafulvalene With Dihalogens and Interhalogens

open access: yesChemistry – A European Journal, EarlyView.
The reactions between tetra(pyridin‐4‐ylthio)tetrathiafulvalene and Br2/I2/ICl/IBr led to a variety of products, including a rare example of neutral 1:4 CT adduct and ionic products showing supramolecular cage motifs at (tri)halide templates. The nature of the reaction products was elucidated based on XRD analysis, Raman spectroscopy and QTAIM, NCI ...
Anna Caria   +6 more
wiley   +1 more source

Embedding a Dinuclear Ru─Pt Photocatalyst Into Polyampholytic Graft Copolymer Matrix Enables Prolonged Hydrogen Evolution While Allowing Catalyst Repair

open access: yesChemistry – A European Journal, EarlyView.
A unimolecular polyampholytic graft copolymer matrix provides a protective confinement for an electrostatically embedded tetrapyridophenazine‐bridged heterodinuclear Ru‐Pt hydrogen evolving photocatalyst. The matrix slows the degradation kinetics of the catalyst and at the same time does not hinder its repair by ammonium persulfate.
Yurii Utievskyi   +10 more
wiley   +1 more source

Volatile Organic Compounds Sensing Using Optical Fibre Long Period Grating with Mesoporous Nano-Scale Coating. [PDF]

open access: yesSensors (Basel), 2017
Hromadka J   +6 more
europepmc   +1 more source

Development of a sustainable water treatment process using biochar as substrate for filtration and coliform removal

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Preparation, modification, and characterization of biochar from woodchips and its application in stream water filtration, evaluated through physicochemical and microbiological analyses. Abstract Global microbial water contamination affects 1.8 billion people, necessitating efficient and sustainable treatment methods.
Tariq Khalil   +8 more
wiley   +1 more source

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