Results 111 to 120 of about 207,343 (281)

Proton Wires in an Electric Field: the Impact of Grotthuss Mechanism on Charge Translocation

, 2004
We present the results of the modeling of proton translocation in finite H-bonded chains in the framework of two-stage proton transport model. We explore the influence of reorientation motion of protons, as well as the effect of electric field and proton
Akeson M, Bjerrum N, Chen M S, Chernyshev A, Cukierman S, Davydov A S, Davydov A S, de Godoy C M G, Eisenberg D, Gennis R B, Pavlenko N I, Phillips L R, Pomès R, Rao C N R, Schumaker M F, Schumaker M F, Stasyuk I V   +16 more
core   +1 more source

Low‐Barrier and Canonical Hydrogen Bonds Modulate Activity and Specificity of a Catalytic Triad

Angewandte Chemie, 2019
AbstractThe position, bonding and dynamics of hydrogen atoms in the catalytic centers of proteins are essential for catalysis. The role of short hydrogen bonds in catalysis has remained highly debated and led to establishment of several distinctive geometrical arrangements of hydrogen atoms vis‐à‐vis the heavier donor and acceptor counterparts, that is,
Prashasti Kumar, Pratul K. Agarwal, M. Brett Waddell, Tanja Mittag, Engin H. Serpersu, Matthew J. Cuneo   +5 more
openaire   +4 more sources

Strain‐Programmable Luminescent Adhesive Patch With Tartrazine‐Mediated Optical Skin Clearing for Photochemical Tissue Bonding

Advanced Functional Materials, EarlyView.
We propose a suture‐complementary approach that integrates optical skin clearing with a strain‐programmable luminescent adhesive patch. Hyaluronic acid promotes transdermal delivery of tartrazine to improve optical clearing and stabilizes its interaction with a photosensitizer. Optical clearing increases the penetration depth of visible light into skin,
Seong‐Jong Kim, Kyungjoo Jo, Kwanghyeon Park, Jun Hee Kim, Jong Hyeong Cho, Inhoo Choi, Sei Kwang Hahn   +6 more
wiley   +1 more source

Insigths into the tribochemistry of silicon-doped carbon based films by ab initio analysis of water/surface interactions

, 2015
Diamond and diamond-like carbon (DLC) are used as coating materials for numerous applications, ranging from biomedicine to tribology. Recently, it has been shown that the hydrophilicity of the carbon films can be enhanced by silicon doping, which highly ...
Kajita, Seiji, Righi, M. C.
core   +1 more source

Strategies for Loading and Releasing Peptide Therapeutics in Biodegradable Carriers

Advanced Functional Materials, EarlyView.
A biodegradable carrier‐based peptide delivery system is a powerful treatment platform for diverse diseases, owing to its superior therapeutic efficacy and low toxicity. This review examines the conventional peptide‐loaded carrier fabrication process and its current limitations.
Wookyoung Jang, Ki Wan Bong
wiley   +1 more source

Oxygen‐Tunnel Indium Tin Oxide Vertical Channel Transistors with Enhanced Current Density and Reliability for Monolithic 3D Compute‐In‐Memory Systems

Advanced Functional Materials, EarlyView.
Oxygen‐tunnel (OT) indium tin oxide (ITO) vertical channel transistors (VCTs) enable reliable, high‐density gain‐cell memory for monolithic 3D integration. A sandwiched SiN/SiO2/SiN OT stack selectively regulates oxygen transport, suppressing parasitic electrode oxidation while stabilizing channel oxygen vacancies, thereby suppressing carrier injection
Hyeonho Gu, Haksoon Jung, Yongwoo Lee, Hoichang Jeong, Yanfeng Zhao, Heesoo Yang, Minho Park, Hyeonjin Lee, Seunghun Baek, Minju Song, Junghwan Kim, Youngmin Jo, Hyunjin Park, Munhyeon Kim, Jae‐Joon Kim, Kyuho Jason Lee, Byungjo Kim, Jimin Kwon   +17 more
wiley   +1 more source

Modulating Iridium Electronic Structure With High‐Valent Metal Doping for Efficient and Durable Acidic Oxygen Evolution Reaction

Advanced Functional Materials, EarlyView.
We synthesized a novel IrCuOx/MnO2 heterostructure co‐doped with high‐valent W and Mo atoms, achieving exceptional acidic stability and high mass activity. Owing to the synergistic effects of structural and electronic modulation, cooperative charge redistribution occurs across both the interface and the lattice.
Minseo Kim, Yeonsu Han, Saleem Sidra, Seokgyu Kim, Ta Thi Thuy Nga, Kainat Talat, Eunji Lee, Hyun Ko, Joosung Kim, Soyun Oh, Jungsue Choi, Silambarasan Perumal, Umair Muhammad, Minsu Kim, Dong ho Lee, Chung‐Li Dong, Do Hwan Kim, Hyoyoung Lee   +17 more
wiley   +1 more source

Understanding β-Hydride Eliminations from Heteroatom Functional Groups [PDF]

, 2011
Using density functional theory, we investigated detailed aspects of the quintessential organometallic process, β-hydride elimination (BHE). In general, we find that most BHE processes from alkyl functional group β-atoms are facile, while BHE processes ...
Goddard, William A. III, Theofanis, Patrick L.   +1 more
core   +1 more source

Receptor‐Free Identification of Toxic Gases Enabled by Hygroscopic Aqueous Salt Films

Advanced Functional Materials, EarlyView.
Water as a gas sensor coating sounds impossible—until it stops evaporating. Here, hygroscopic salt solutions (LiCl, LiBr, H3PO4) form non‐drying aqueous films on CNT chemiresistors under ambient air. Gases partition into these liquid layers, sometimes transforming into water, and generate salt‐specific resistance fingerprints across a four‐channel ...
Seongwoo Lee, Yun‐Tae Kim, Hwarang Choi, Sanghwan Park, Seongyeop Lim, Chang Young Lee   +5 more
wiley   +1 more source

Light‐Promoted Hydrazine Dehydrogenation over Ni/NH2‐MIL‐125: Unraveling Mechanisms for Efficient Hydrogen Production

Advanced Science
Developing efficient, low‐cost, and durable catalysts for the complete dehydrogenation of hydrous hydrazine (N2H4·H2O) remains a significant challenge.
Jianjun Long, Caili Hu, Qilu Yao, Kun Wang, Gang Feng, Shaowen Cao, Zhang‐Hui Lu   +6 more
doaj   +1 more source