Results 221 to 230 of about 1,457,064 (320)

Counterintuitive Fluorescence Blue Shift in Symmetry Breaking Dicationic Bis(indolium) with Two‐Photon Absorption Properties for NIR Living Cell Imaging

Advanced Materials, EarlyView.
Highly water‐soluble dicationic bis(indolium) dyes have been prepared, showing excellent two‐photon absorption and light emission. Their fluorescence behavior discloses an unusual increasing blue shift with increasing solvent polarity, which, in parallel, is beneficial for enhanced detection in biological media.
Carlos Benitez‐Martin, Jose M. Marin‐Beloqui, Juan T. López Navarrete, Juan Casado, Francisco Najera, Ezequiel Perez‐Inestrosa   +5 more
wiley   +1 more source

Bioorthogonal Photoactivation of 2‐Nitrobenzyl Caged Doxorubicin Anticancer Prodrugs on Gold Nanostars

Advanced Materials, EarlyView.
Bioorthogonal chemistry was applied to intracellularly photoactivate Doxorubicin (Dox) using gold nanostars (AuNSt) and near‐infrared (NIR) light. Two prodrugs were used: one photoactivatable, masked with 2‐nitrobenzyl carbamate (proDox1) and another photolabile, masked with 2‐nitrobenzyl diol (proDox2), which was attached to the AuNSt surface.
Juan José Esteve‐Moreno, Andrea Escudero, Oscar Ferreira Silvestre, José Manuel Terrés, Mónica Gorbe, Eva Garrido, Carlos Renero‐Lecuna, Judith Langer, María Alfonso, Javier Ibañez, Félix Sancenón, Roberto Cao‐Milán, Luis M. Liz‐Marzán, Alba García‐Fernández, Andy Hernández‐Montoto, Ramón Martínez‐Máñez   +15 more
wiley   +1 more source

Water Permeates and Plasticizes Amorphous Carbon Dots: Unraveling the Inner Accessibility of the Nanoparticles by Glass Transition Studies

Advanced Materials, EarlyView.
The water permeability of amorphous carbon dots (CDs) is demonstrated by investigating their plasticization. Novel polyamide‐based and amorphous nanoparticles are synthesized by controlling their inner packing density. Water plasticization is evidenced by the decrease of the CDs glass transition temperature with increasing the hydration degree.
Elisa Sturabotti, Valerio Di Lisio, Lucia Cardo, Alessandro Camilli, Estela Moretón Alfonsín, Daniele Cangialosi, Amaia Iturrospe Ibarra, Arantxa Arbe, Maurizio Prato   +8 more
wiley   +1 more source

Revealing How Acid Sites Enhance the Electrocatalytic Glycerol Oxidation Performance on Pt Loaded Zeolite‐Carbon Composite Materials

Advanced Materials, EarlyView.
In the work reported herein, the catalytic effects of acid sites on electrocatalytic glycerol oxidation reaction are investigated by using a novel catalytic material system that integrates Pt metal sites with acidic Al sites. Abstract The catalytic role and function of acid sites in solid acid catalysts, such as zeolites, are well understood in the ...
Ju Ye Kim, Sunjae No, Jinwoo Hwang, Mi Yoo, Hakju Lee, Youngbi Kim, Youngmin Kim, Yong Tae Kim, Jeong‐Chul Kim, Jeong Woo Han, Kyoungsoo Kim, Hyung Ju Kim   +11 more
wiley   +1 more source

Benchtop NMR in Biomedicine: An Updated Literature Overview. [PDF]

Metabolites
Fantato L, Salobehaj M, Patrussi J, Meoni G, Vignoli A, Tenori L.   +5 more
europepmc   +1 more source

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

Advanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez, Alejandro Orellana‐Silla, Marta Galbiati, Efrén Navarro‐Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio‐Giménez, Sergio Tatay, Carlos Martí‐Gastaldo   +9 more
wiley   +1 more source

Adiabatic Heteronuclear Isotropic Mixing in Low-Field Nuclear Magnetic Resonance. [PDF]

J Phys Chem Lett
Zhang Z, Hilty C.
europepmc   +1 more source

Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

Advanced Materials, EarlyView.
Crystal engineering enables systematic study of structure/function relationships as exemplified by pore engineering of reticular sorbents, including porous coordination networks and covalent organic frameworks. This review assesses such studies applied across the full scope of industrially relevant hydrocarbon separations to provide insight into how ...
Xia Li, Soumya Mukherjee, Michael J. Zaworotko   +2 more
wiley   +1 more source

Additive Manufacturing of Molecular Architecture Encoded Stretchable Polyethylene Glycol Hydrogels and Elastomers

Advanced Materials, EarlyView.
Bottlebrush molecular architecture prevents the crystallization of high molecular weight polyethylene glycol (PEG) based polymers, enabling highly stretchable photocurable PEG hydrogels and elastomers for high‐performance conductive solvent‐free electrolytes at room temperature and for additive manufacturing of complex architectures and multi‐material ...
Baiqiang Huang, Myoeum Kim, Pu Zhang, Emmanuel Oduro, Daniel A. Rau, Li‐Heng Cai   +5 more
wiley   +1 more source

Detection Limits of Blood Metabolites at Physiological Concentrations Using Benchtop $$ {}^1 $$ H NMR. [PDF]

NMR Biomed
Hill AD, Travish G, Phelan M, Hayward M, Welsch CP.   +4 more
europepmc   +1 more source