Results 161 to 170 of about 8,204 (174)
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Microcalorimetric Study of the Effects of a Chaotropic Salt, KSCN, on the Lower Critical Solution Temperature (LCST) of Aqueous Poly(N-isopropylacrylamide) (PNIPA) Solutions

Macromolecules, 2009
The LCST phase-transition of aqueous PNIPA solutions in rising concentrations of the strong chaotropic salt KSCN was studied microcalorimetrically by DSC and apparently for the first time by ITC. An endothermic (entropy driven) binding of KSCN onto PNIPA was observed, explained by electrostatic perturbation of hydrophobic hydration by adsorbed ions.
Inna Shechter   +4 more
openaire   +1 more source

Thermoresponsive light scattering device utilizing surface behavior effects between polyimide and an ionic liquid-water mixture exhibiting lower critical solution temperature (LCST)-type phase separation

Journal of Applied Physics, 2018
We proposed a thermoresponsive light scattering device that utilizes the surface behavior between polyimide and an ionic liquid-water mixture exhibiting lower critical solution temperature (LCST)-type phase separation. The LCST behavior for an ionic liquid device utilizing the polyimide with and without alkyl side chains was investigated.
Kazuya Goda   +3 more
openaire   +1 more source

Synthesis of thermoreversible polymers by aminolysis of poly(methyl 2‐(N‐acryloylamino)‐2‐methoxyacetate): Correlations of the lower critical solution temperatures (LCST) with the side group structures and the salt concentration in aqueous systems

Macromolecular Rapid Communications, 1994
Thermoreversible comblike polymers (CH 2 CH[CONHCH(OMe)CONHR]) n and (CH 2 CH[CONHCH(OMe)CONHC 3 H 7 ) x (CH 2 CH[CONHCH(OMe)CONH(CH 2 ) 2 OMe]) y (R= iPr, n-Bu, (CH 2 ) 2 OMe, (CH 2 ) 3 OMe, (CH 2 ) 3 OEt; x/y= 0.25, 0.33, 0.4, 0.5, 0.6, 0.67, 0.75) are synthesized by aminolysis and their LCST in saline aqueous solution is investigated as a function
Helmut Ritter, Anja Stock
openaire   +1 more source

Block copolymer micelles with lower critical solution temperature (LCST) as novel stimuli-responsive systems in heterogeneous systems based on ionic liquids

Polymer Preprints, 2008
The triblock copolymer, 2-nonyl-2-oxazoline-2-ethyl-2-oxazoline-2-methyl-2-oxazoline triblock copolymer, forms micelles in water/BMIM-PF6 ionic liq. systems. The micelles exhibit thermoreversible phase transfer behavior and may offer a simple means to transport chems. back and forth between two immiscible phases. [on SciFinder (R)]
Guerrero Sanchez, C.A.   +2 more
openaire   +2 more sources

A QSPR study for predicting θ(LCST) and θ(UCST) in binary polymer solutions

Chemical Engineering Science, 2023
Xue-Qing Gong   +2 more
exaly  

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