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A linear solvation energy relationship (LSER) was developed to predict the partitioning of neutral chemicals from polysorbate 80 (PS 80) micelles to water. Predicted partition coefficients were converted to a concentration dependent solubilization strength of aqueous PS 80 solutions.
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Tautomerism in some aromatic Schiff bases and related azo compounds: an LSER study
Journal of Physical Organic Chemistry, 2005An LSER study on the tautomerism of some aromatic Schiff bases and related azo compounds has vindicated the picture presented by previous ab initio studies and added further detail of its own. As predicted, the aminoenone tautomer is always the more polar (positive π* term) and, in addition, is specifically favoured by proton donor solvents (α term ...
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