Results 71 to 80 of about 2,804 (173)

Fluorogenic Sydnones for Bioorthogonal Labeling of DNA

Chemistry – A European Journal, EarlyView.
Conjugates of sydnones with cyanine‐styryl dyes combine bioorthogonal reactivity with fluorogenicity. The reactivity with bicyclo[6.1.0]non‐4‐yne (BCN)‐modified DNA showed second‐order rate constants of up to k2 = 2,300 M−1s−1 and fluorescence turn‐on by one magnitude of order.
Kerstin Müller, Hans‐Achim Wagenknecht   +1 more
wiley   +1 more source

Anisotropy Factor Spectra for Weakly Allowed Electronic Transitions in Chiral Ketones

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Anisotropy factor spectra for the weak n→π*‐type A‐band of chiral ketones cannot be described within the Franck–Condon approximation. Thus, we present such spectra computed by accounting for Herzberg–Teller corrections and compare them to experiments for fenchone, camphor and 3MCP to describe chiroptical properties of these molecules in the mid to near
Leon A. Kerber, Oliver Kreuz, Tom Ring, Hendrike Braun, Robert Berger, Daniel M. Reich   +5 more
wiley   +1 more source

Ultrafast Transitions in X‐Ray Irradiated Solids

Contributions to Plasma Physics, EarlyView.
ABSTRACT In this review, we present current developments on modeling ultrafast transitions in solids triggered by intense, atto‐ to femtosecond pulses from X‐ray free electron lasers. This specific irradiation regime requires dedicated simulation tools based on theoretical and computational methods, involving the elements of classical and quantum ...
Sebastião Antunes, Konrad J. Kapcia, Vladimir Lipp, Beata Ziaja   +3 more
wiley   +1 more source

Elementary Steps of Energy Conversion in Strongly Correlated Systems: Beyond Single Quasiparticles and Rigid Bands

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This article reviews the fundamental consequences of strong correlations on excitations and elementary steps of energy conversion leading to new opportunities to control energy conversion. Examples include friction at surfaces, thermal transport, and photovoltaic energy conversion.
Vasily Moshnyaga, Peter E. Blöchl, Vitaly Bruchmann‐Bamberg, Annika Dehning, Lukas Allen‐Rump, Christopher Hausmann, Matthias Krüger, Amrith Rathnakaran, Sangeeta Rajpurohit, Daniel Steil, Christoph Flathmann, Jörg Hoffmann, Michael Seibt, Cynthia Volkert, Christian Jooss   +14 more
wiley   +1 more source

Enhancing the Ferroelectricity of MAPbI3 via Hydroxyl Groups to Boost Photocatalytic Performance

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The hydroxyl groups in (EOA)2PbBr4 enable a rearrangement of the polar MA+ ions in MAPbI3, which enhances the Ps‐electric field and promotes the separation of photogenerated carriers. Consequently, the (EOA)2PbBr4/MAPbI3 composite exhibits the enhanced CO production yield in photocatalytic CO2 reduction reactions.
Zhaohui Fang, Zhihan Yu, Yulong Liao, Yuanxun Li, Minshu Chen, Yuan Teng, Quanjun Xiang   +6 more
wiley   +1 more source

Dimensional Engineering of Wet‐Spun MOF‐Based Woven Fabrics for Superior Electromagnetic Wave Absorption

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work fabricated MOF‐based woven absorbing fabrics with dimensional engineering via a wet spinning strategy. The absorbing fabrics achieve a reflection loss of −51.47 dB at 2.9 mm, with an effective absorption bandwidth reaching 3.54 GHz. The absorbing fabrics can be freely bent, stretched, and folded, with individual fibers exhibiting a break ...
Zihao Yan, Liyuan Guan, Qing Liu, Junhao Lin, Jianyong Yu, Bin Ding, Zhaoling Li   +6 more
wiley   +1 more source

Three Birds with One Stone: High‐Performance 2D Lead‐Free Perovskite Solar Cells via Direct In Situ Generation of Organic‐Spacer Precursors

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Adopting a “three birds with one stone” strategy, the in situ generation of organic spacer simultaneously addresses three major challenges limiting 2D tin‐based perovskites: (1) Sn2+ oxidation; (2) rapid crystallization; and (3) uncontrolled 2D phase distribution.
Yifan Shen, Yanfeng Chen, Quan Chen, Jinyu Wu, Jian Yang, Erdong Zhang, Wei Wang, Ningyi Xu, Wei Shen, Junmin Xia, Shufen Chen, Wei Huang   +11 more
wiley   +1 more source

Switchable Dual Emission of Luminescent Metal–Organic Framework@Nanoparticle Composites of EuBDC and ZrO‐Containing Hybrid Materials

European Journal of Inorganic Chemistry, EarlyView.
Luminescent metal–organic framework@nanoparticle composites show dual emission of both components EuBDC and zirconyl‐containing nanoparticles, being reversible, excitation energy‐dependent and solvatochromic switches. The chromaticity changes are fast, as no chemical transformation is involved and required as source of the dual emission.
Tobias Wehner, Joachim G. Heck, Claus Feldmann, Klaus Müller‐Buschbaum   +3 more
wiley   +1 more source

Magneto‐responsive fibers and fabrics for soft systems

FlexMat, EarlyView.
Abstract The combination of functional materials in fiber form has led to a surge in the integration of functional fibers and fabrics into soft systems that span sensing, communication, and actuation domains. A key subset is magnetic fibers and fabrics.
Hanlin Zhu, Jingxian Cui, Qingchao Fan, Zefeng Zhang, Chao Jiang, Hwa‐Yaw Tam, Yan Zhao, Zhe Wang, Zhixun Wang   +8 more
wiley   +1 more source

Nuclear‐Spin Hyperpolarization of Biomolecules by Optically Enhanced NMR at Ultra‐High Field

Journal of the Chinese Chemical Society, EarlyView.
This study shows that the sensitivity of liquid‐state NMR spectroscopy can be dramatically increased, with enhancement factors up to 160‐fold on a 1.1 GHz ultra‐high‐field NMR spectrometer. This advance exploits low‐concentration photochemically induced dynamic nuclear polarization (LC‐photo‐CIDNP) and it enables facile atomic‐resolution detection of ...
Ji Ho Jeong, Anubhab Halder, Silvia Cavagnero   +2 more
wiley   +1 more source