Results 141 to 150 of about 1,562,446 (293)

5-Methyl-cytosine stabilizes DNA but hinders DNA hybridization revealed by magnetic tweezers and simulations. [PDF]

open access: yesNucleic Acids Res, 2022
Zhao XC   +8 more
europepmc   +1 more source

Developing a Suitable Anion Exchange Layer Structure for Pure–Water Fed Bipolar Membrane CO2 Electrolysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A porous anion exchange layer (AEL) is implemented in a forward‐biased bipolar membrane CO2 electrolyzer to suppress carbonate crossover, support CO2 regeneration and maintain cathode alkalinity. Two fabrication strategies are compared—deposition on a silver gas diffusion electrode (GDE) or on the CEM—showing that a porous AEL‐coated GDE provides the ...
Henning Lorenz   +3 more
wiley   +1 more source

Sprayable Polyolefin Sorbents Enabled by Bio‐Solvents for Large‐Scale Oil and Chemical Spill Recovery

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A sprayable POE‐based sorbent formulated with a green solvent blend of α‐pinene, D‐limonene, and p‐cymene enables rapid in situ film formation via solvent evaporation, allowing efficient pollutant capture. The system exhibits high oil uptake (37.3 g g−1) and effectively removes up to 60 mL of VLSFO under simulated marine spill conditions.
Youngmin Choi, Changwoo Nam
wiley   +1 more source

Chemically Modular, Nonfluorinated Polymer Adsorbents for Capturing Per‐ and Polyfluoroalkyl Substances (PFAS)

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nonfluorinated polymer networks for PFAS adsorption are synthesized using active ester click chemistry. Incorporating Lewis base ligands along with hydrophilic and hydrophobic co‐monomers leads to high PFOA binding efficiency. Ligand basicity and pH are found to play an important role in PFOA sorption.
Lakshay K. Dhamania, Joshua D. Moon
wiley   +1 more source

Single-molecule multiplexed profiling of protein-DNA complexes using magnetic tweezers. [PDF]

open access: yesJ Biol Chem, 2021
Liang L   +11 more
europepmc   +1 more source

Magnetic tweezers for captive disclination loops

open access: yes, 2019
Disclination loops threaded on a polymeric fiber with planar axial anchoring are shown to be sensitive to magnetic fields. In particular, a homogeneous magnetic field oblique to the fiber drives translation of disclination loops along it. The velocity of
Maria Helena Godinho   +5 more
core   +1 more source

Ligand Redox Noninnocence in Bis(phosphinimine) Diarylamido Pincer Complexes of Nickel

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The oxidative noninnocence of a bis(phosphinimine) ligand featuring a diarylamido backbone was investigated for several nickel complexes. Radical/charge delocalization across the aromatic backbone plays an important role in the stabilization of the diarylaminyl and putative diarylnitrenium complexes.
Xiujing Xing   +8 more
wiley   +1 more source

Sustainable Iron Catalysis for Chemodivergent Oxidation of Lignin‐Based Vanillyl Alcohol: Selective Access to Vanillin and Vanillic Acid

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota   +2 more
wiley   +1 more source

Meniscus‐guided organic semiconductor single crystals: From fluid dynamics to morphology control and multifunctional applications

open access: yesFlexMat, EarlyView.
Centered on the multiscale meniscus, this review dissects mass transport in meniscus‐guided coating into parallel and lateral components. By analyzing the balance of multiple factors during crystallization, it establishes a clear morphology‐performance relationship.
Yumeng Wang   +7 more
wiley   +1 more source

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