Results 211 to 220 of about 231,082 (310)

Phosphoramidate and Silyl Amine Mediated Synthesis of Isocyanide Cyclopentadienone Iron Complexes

open access: yesHelvetica Chimica Acta, EarlyView.
Carbonyl ligands in cyclopentadienone iron complexes are replaced by isocyanide ligands without using free, malodorous isocyanides. The reaction takes place via an Aza‐Wittig‐type reaction starting from primary amines, employing either phosphoramidates or silyl amines as intermediate reagents.
André Bütikofer   +3 more
wiley   +1 more source

Capture of adeno‐associated viruses from clarified lysate by continuous flow ultracentrifugation: a comparative study of iodixanol and sucrose gradients

open access: yesJournal of Chemical Technology &Biotechnology, EarlyView.
Abstract BACKGROUND Adeno‐Associated Virus vectors are widely used in gene therapy due to their safety and efficacy. Despite the interest in their therapeutical application, AAV purification remains a significant challenge. Density gradient ultracentrifugation using cesium chloride, sucrose, or iodixanol gradients are common methods for AAV ...
Sabrina Leigheb   +6 more
wiley   +1 more source

Laser Absorption Shock Tube Study of C1 to C4 n‐Alkyl Formate Pyrolysis

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT n$n$‐Alkyl formates are considered as potential alternative fuels or fuel additives. While their oxidation chemistry has been investigated intensely, their pyrolysis chemistry requires more experimental insights. The present work utilizes shock tube experiments in combination with infrared laser absorption measurements to obtain information ...
Malte Döntgen   +2 more
wiley   +1 more source

The IceShark, an effective method for sampling plankton under sea ice

open access: yesLimnology and Oceanography: Methods, EarlyView.
Abstract Seasonal sea ice plays a crucial role in shaping coastal ecosystem dynamics throughout the circumpolar region. Of particular interest to oceanographers is the ice‐ocean interface which functions as a multidimensional habitat, supporting both sympagic algae and pelagic phytoplankton in the under‐ice surface waters.
Eleanor A. Barry   +4 more
wiley   +1 more source

Shape Derivatives of the Eigenvalues of the De Rham Complex for Lipschitz Deformations and Variable Coefficients: Part I

open access: yesMathematical Methods in the Applied Sciences, EarlyView.
ABSTRACT We study eigenvalue problems for the de Rham complex on varying three‐dimensional domains. Our analysis includes the Helmholtz equation as well as the Maxwell system with mixed boundary conditions and non‐constant coefficients. We provide Hadamard‐type formulas for the shape derivatives under weak regularity assumptions on the domain and its ...
Pier Domenico Lamberti   +2 more
wiley   +1 more source

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