Results 31 to 40 of about 35,072 (269)

The influence of iron-binding ligands in the corrosion of carbon steel driven by iron-reducing bacteria

open access: yesnpj Materials Degradation, 2022
Iron reducing bacteria (IRB) are thought to accelerate the corrosion of steel by removing the Fe(III)-oxide passivating layer through iron respiration.
Alejandra Hernandez-Santana   +2 more
doaj   +1 more source

On the ordeal of quinolone preparation via cyclisation of aryl-enamines; synthesis and structure of ethyl 6-methyl-7-iodo-4-(3-iodo-4-methylphenoxy)-quinoline-3-carboxylate [PDF]

open access: yes, 2017
Recent studies directed to the design of compounds targeting the bc(1) protein complex of Plasmodium falciparum, the parasite responsible for most lethal cases of malaria, identified quinolones (4-oxo-quinolines) with low nanomolar inhibitory activity ...
Bras, Elisa M.   +8 more
core   +1 more source

Genomic characterization of malonate positive Cronobacter sakazakii serotype O:2, sequence type 64 strains, isolated from clinical, food, and environment samples

open access: yesGut Pathogens, 2018
Background Malonate utilization, an important differential trait, well recognized as being possessed by six of the seven Cronobacter species is thought to be largely absent in Cronobacter sakazakii (Csak). The current study provides experimental evidence
Gopal R. Gopinath   +26 more
doaj   +1 more source

Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones [PDF]

open access: yes, 2006
The regioselectivity of malonate addition to (3-methylpentadienyl)Fe(CO)3+ is controlled by the malonate−counterion association. The Li+ salt of malonate proceeds via C1 nucleophilic attack to afford the 1,3Z-diene complex 4a, while reaction of highly ...
Chaudhury, Subhabrata   +1 more
core   +1 more source

Synergistic Visible Light Nanophotocatalysis and Asymmetric Organocatalysis for the Stereoselective α‐Alkylation of Aldehydes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
An unprecedent dual catalytic nanophotocatalytic and asymmetric organocatalytic system for the α‐functionalization of aldehydes is developed using carbon nanodots as photosensitizers. The optimized methodology yields the alkylated products with up to 94% yield and up to 98:2 e.r., evidencing the possible recycling of the nanocatalysts.
Antonio Di Sabato   +9 more
wiley   +1 more source

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

open access: yesFrontiers in Chemistry, 2019
Five new Lanthanide(III) complexes of malonic acid (HOOC-CH2-COOH); {[Gd(C3H2O4)(H2O)4]·NO3}n (1), {[Tb(C3H2O4)(H2O)4]·NO3}n (2), {[Ho(C3H2O4)(H2O)4]·NO3}n (3), [Er(C3H2O4)(C3H3O4)(H2O)2]n (4), and {[Eu2(C3H2O4)2(C3H3O4)2(H2O)6]·4H2O}n (5) were ...
Sajjad Hussain   +8 more
doaj   +1 more source

Trypanocidal action of bisphosphonium salts through a mitochondrial target in bloodstream form Trypanosoma brucei [PDF]

open access: yes, 2015
Lipophilic bisphosphonium salts are among the most promising antiprotozoal leads currently under investigation. As part of their preclinical evaluation we here report on their mode of action against African trypanosomes, the etiological agents of ...
Alkhaldi, Abdulsalam A.M.   +5 more
core   +2 more sources

Inhibiting FAT1 Blocks Metabolic Bypass to Enhance Antitumor Efficacy of TCA Cycle Inhibition through Suppressing CPT1A‐Dependent Fatty Acid Oxidation

open access: yesAdvanced Science, EarlyView.
This study demonstrates that mutant FAT1 promotes ASCL2‐driven, CPT1A‐dependent fatty acid oxidation, leading to resistance to CPI‐613‐mediated TCA cycle inhibition in head and neck cancer. In vivo gene depletion of mutant FAT1 with LNP‐sgFAT1 suppresses tumor growth and restores CPI‐613 sensitivity, revealing a targetable metabolic bypass with ...
Fanghui Chen   +11 more
wiley   +1 more source

Crystal structure of poly[diaqua(μ-2-carboxyacetato-κ3O,O′:O′′)(2-carboxyacetato-κO)di-μ-chlorido-dicobalt(II)]

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2]n, comprises one CoII atom, one water molecule, one singly deprotonated malonic acid molecule (HMal−; systematic name 2-carboxyacetate) and one Cl− anion.
Yasmina Bouaoud   +5 more
doaj   +1 more source

Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations [PDF]

open access: yes, 2007
The title cations (9 and 12) were prepared by dehydration of (3-methyl-2,4-pentadien-1-ol)Fe(CO)2L+ complexes. The structure of the (CO)2PPh3-ligated 12 was determined by single-crystal X-ray analysis. Reaction of carbon and heteroatom nucleophiles to (3-
Bennett, Dennis W   +5 more
core   +1 more source

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