Asymmetric Mannich Reaction of Malonates with Imines Catalyzed by a Chiral Calcium Complex
A chiral calcium complex was found to be effective for the Mannich reactions of malonates with N-Boc imines. The desired adducts were obtained in excellent yields (up to 95%) with moderate to good enantioselectivities (up to 77% ee)
Thomas Poisson (1627144) +3 more
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SYNTHESIS OF BENZOFURANONES VIA MALONATES DESYMMETRIZATION
SYNTHESIS OF BENZOFURANONES VIA MALONATES DESYMMETRIZATION. S. Placidi,a A. Puglisi,a C. Giustini,a A. Ricucci,a E. Perrotti,a L. Massaro,a D. Morra,a F. Ciucci,a A. Zucchet,a A. Antenucci,a M. Moliterno,a R. Salvio,a,b M.
a +13 more
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Mechanistic Elucidation and Stereochemical Consequences of Alternative Binding of Alkenyl Substrates by Engineered Arylmalonate Decarboxylase. [PDF]
van der Pol E +14 more
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Enantioselective Addition of Dialkyl Malonates to β-Arylethenesulfonyl Fluorides under High-Pressure Conditions. [PDF]
Kopyt M +3 more
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DoE-Based Optimization of a Photocatalytic C‑Alkylation Reaction in a 3D-Printed Photoreactor. [PDF]
Richter D +7 more
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Reverse Weak Polarity-Induced Ordered Layer Control for Enhanced Second-Harmonic Generation in Ultraviolet Nonlinear Optical Crystals. [PDF]
Wu L +7 more
europepmc +1 more source
Enantioselective cyclization reactions involving 3-isothiocyanato oxindoles: synthesis of spirocycles. [PDF]
Edareh MH +4 more
europepmc +1 more source
Reductant-Free NiF<sub>2</sub>/Picolinic Acid-Catalyzed Coupling-Cyclization of 2-Iodobenzamides with Malonates. [PDF]
Tanomsiri G +4 more
europepmc +1 more source
Co-Translational Incorporation of (<i>R</i>)- and (<i>S</i>)-β<sup>2</sup>-Hydroxyacids <i>In Vivo</i>: Directed Evolution of Efficient Aminoacyl-tRNA Synthetases. [PDF]
Soni C +8 more
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