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Advances in Asymmetric Organocatalysis Over the Last 10 Years

Nature Communications, 2020
Organocatalysis has become a major pillar of (asymmetric) catalysis. Here, the authors discuss recent trends in organocatalytic activation modes for challenging stereoselective transformations and the emerging integration with other fields, such as ...
Bin Tan, Shao-Hua Xiang
exaly   +2 more sources

Enantioselective cyclization reactions involving 3-isothiocyanato oxindoles: synthesis of spirocycles [PDF]

RSC Advances
Recently, 3-isothiocyanato oxindoles have been used in various asymmetric cascade cyclization reactions for the synthesis of biologically important spirocyclic compounds.
Mohammad Hadi Edareh, Fatemeh Doraghi, Arman Farahani, Mehran Ghasemi, Mohammad Mahdavi   +4 more
doaj   +2 more sources

Recent advancements in visible light-induced, vitamin-catalysed chemical transformations [PDF]

RSC Advances
Vitamins play a vital role in organic transformations, particularly in the field of organocatalysis. Vitamins have been found to function as photoredox catalysts in an array of synthetic processes, supporting advancements in the realm of photocatalysis ...
Shraddha Tivari, Surendra Kumar Jaiswal, Bankelal Yadav, Anand Pandey, Rohit Kumar, Pravin K. Singh, Praveen P. Singh, Vishal Srivastava   +7 more
doaj   +2 more sources

Enantioselective radical chemistry: a bright future ahead [PDF]

Beilstein Journal of Organic Chemistry
This perspective is focused on enantioselective free radical reactions. It describes several important catalytic asymmetric strategies applied to enantioselective radical reactions, including chiral Lewis acid catalysis, organocatalysis, photoredox ...
Anna C. Renner, Sagar S. Thorat, Hariharaputhiran Subramanian, Mukund P. Sibi   +3 more
doaj   +2 more sources

Organocatalysts for enantioselective synthesis of fine chemicals: definitions, trends and developments

ScienceOpen Research, 2015
Organocatalysis, that is the use of small organic molecules to catalyse organic transformations, has been included among the most successful concepts in asymmetric catalysis and it has been used for the enantioselective construction of C-C, C-N, C-O, C-S,
Chiara Palumbo
doaj   +5 more sources

Recent Advances in the Enantioselective Radical Reactions

Molecules, 2023
The review covers research published since 2017 and is focused on enantioselective synthesis using radical reactions. It describes recent approaches to the asymmetric synthesis of chiral molecules based on the application of the metal catalysis, dual ...
Tomasz Bauer, Yusuf Zaim Hakim, Paulina Morawska   +2 more
doaj   +1 more source

Electroredox carbene organocatalysis with iodide as promoter

Nature Communications, 2022
Oxidative carbene organocatalysis has been developed as a versatile synthetic method, but has been paired with electroredox chemistry in only limited examples.
Peng Zhou, Wenchang Li, Jianyong Lan, Tingshun Zhu   +3 more
doaj   +1 more source

Evolution of design approaches in asymmetric organocatalysis over the last decade

Tetrahedron Chem, 2023
This perspective intends to cover the vast field of asymmetric organocatalysis and its evolution during the last ten years. This work has evaluated the corresponding timeline of the progression of the field concerning the main synthetic approaches as ...
Nika Melnyk, Marianne Rica Garcia, Iñigo Iribarren, Cristina Trujillo   +3 more
doaj   +1 more source

Molecular Understanding and Practical In Silico Catalyst Design in Computational Organocatalysis and Phase Transfer Catalysis—Challenges and Opportunities

Molecules, 2023
Through the lens of organocatalysis and phase transfer catalysis, we will examine the key components to calculate or predict catalysis-performance metrics, such as turnover frequency and measurement of stereoselectivity, via computational chemistry.
Choon Wee Kee
doaj   +1 more source

New advances in asymmetric organocatalysis II [PDF]

Beilstein Journal of Organic Chemistry
Radovan Šebesta
doaj   +2 more sources