Results 11 to 20 of about 6,809 (215)
Organocatalysis Chemistry in Flow [PDF]
Current Organocatalysis, 2015 The last decade has witnessed a huge growth in the use of flow chemistry as wellestablished procedure for performing chemical transformations; indeed, under continuous flow conditions, more sustainable, safer and easier scalable processes could be developed with respect to conventional batch procedures.
A. Puglisi +3 more
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Theoretical Perspectives in Organocatalysis [PDF]
Chemistry – A European Journal, 2022 AbstractIt is clear that the field of organocatalysis is continuously expanding during the last decades. With increasing computational capacity and new techniques, computational methods have provided a more economic approach to explore different chemical systems.
Nika Melnyk +3 more
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Do We Need Asymmetric Organocatalysis? [PDF]
CHIMIA, 2007 Asymmetric organocatalysis is a 'fast lane' of the chemical highway: the progress in the last decade is simply spectacular. This introductory article summarizes basic principles, historical background, and discusses basic catalyst classes and ...
Peter I. Dalko
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Synergistic Organo‐Organocatalysis [PDF]
, 2023 Asymmetric organocatalysis is pivotal in the field of asymmetric catalysis and is a crucial technology platform in the industry. However, in some cases, catalysis may have reached its limit and synergistic catalysis is an interesting groundbreaking ...
Pesciaioli, Fabio +3 more
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Halogen-Bond-Based Organocatalysis Unveiled: Computational Design and Mechanistic Insights [PDF]
, 2023 Halogen-bond-based organocatalysis is a promising alternative to the extensively explored halogen-bond-based catalysis. This paper presents a comprehensive theoreti- cal investigation of the structural and electronic properties of the σ-hole, as well as ...
Nika, Melnyk +2 more
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On Rational Design of Stereodivergent Organocatalysis Controlled by Selective Hydration [PDF]
, 2023 Stereodivergent asymmetric synthesis via slightly tuning the catalytic conditions is very attractive for early-stage drug discovery, because it is a very time efficient and economical method for obtaining all potential biologically active diastereomers ...
Liuqun, Gu
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Understanding chiral proton organocatalysis using cinchonium derivatives [PDF]
, 2023 This work presents a detailed mechanistic study of a quininium-catalyzed aza-Michael reaction, providing essential infor-mation for the development of reactions in chiral proton organocatalysis (CPO).
Raquel, P. Herrera +4 more
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Evolution of design approaches in asymmetric organocatalysis over the last decade
Tetrahedron Chem, 2023 This perspective intends to cover the vast field of asymmetric organocatalysis and its evolution during the last ten years. This work has evaluated the corresponding timeline of the progression of the field concerning the main synthetic approaches as ...
Nika Melnyk +3 more
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Phosphine Organocatalysis [PDF]
Chemical Reviews, 2018 The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a phosphine to an electrophilic starting material, producing a reactive zwitterionic intermediate, generally under mild conditions. In this Review, we classify nucleophilic phosphine catalysis reactions in terms of their electrophilic components. In the majority of
Hongchao Guo +4 more
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Organocatalysis emerging as a technology [PDF]
, 2021 During the last 20 years, organocatalysis has significantly advanced as a field. Thanks to contributions from hundreds of groups and companies around the world, the area has risen from a few mechanistically ill-defined niche reactions, to one of the most
List, B., Aukland, M.
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