Results 31 to 40 of about 7,915 (201)
Understanding chiral proton organocatalysis using cinchonium derivatives [PDF]
This work presents a detailed mechanistic study of a quininium-catalyzed aza-Michael reaction, providing essential infor-mation for the development of reactions in chiral proton organocatalysis (CPO).
Raquel, P. Herrera +4 more
core +1 more source
Evolution of design approaches in asymmetric organocatalysis over the last decade
This perspective intends to cover the vast field of asymmetric organocatalysis and its evolution during the last ten years. This work has evaluated the corresponding timeline of the progression of the field concerning the main synthetic approaches as ...
Nika Melnyk +3 more
doaj +1 more source
Phosphine Organocatalysis [PDF]
The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a phosphine to an electrophilic starting material, producing a reactive zwitterionic intermediate, generally under mild conditions. In this Review, we classify nucleophilic phosphine catalysis reactions in terms of their electrophilic components. In the majority of
Hongchao Guo +4 more
openaire +4 more sources
Through the lens of organocatalysis and phase transfer catalysis, we will examine the key components to calculate or predict catalysis-performance metrics, such as turnover frequency and measurement of stereoselectivity, via computational chemistry.
Choon Wee Kee
doaj +1 more source
Synergistic Organo‐Organocatalysis
Asymmetric organocatalysis is pivotal in the field of asymmetric catalysis and is a crucial technology platform in the industry. However, in some cases, catalysis may have reached its limit and synergistic catalysis is an interesting groundbreaking ...
Pesciaioli, Fabio +3 more
core +1 more source
Organocatalysis emerging as a technology [PDF]
During the last 20 years, organocatalysis has significantly advanced as a field. Thanks to contributions from hundreds of groups and companies around the world, the area has risen from a few mechanistically ill-defined niche reactions, to one of the most
List, B., Aukland, M.
core +1 more source
New advances in asymmetric organocatalysis II [PDF]
Radovan Šebesta
doaj +2 more sources
Solvent-free asymmetric organocatalyzed reactions: a strategy towards a greener organocatalysis According with the principles of “green” chemistry, asymmetric organocatalysis aims to become a sustainable strategy to catalyze a wide range of chemical ...
José G. Hernández, Eusebio Juaristi
doaj +1 more source
Peptide catalyzed conjugate addition reactions of aldehydes to nitroolefins [PDF]
In this thesis mechanistic investigations into the peptide catalyzed conjugate addition reaction between aldehydes and nitroolefins are described.
Duschmalé, Jörg
core +1 more source
Switchable organocatalysis from N-heterocyclic carbene-carbodiimide adducts with tunable release temperature [PDF]
N-Heterocyclic carbenes (NHCs) are powerful organocatalysts, but practical applications often require in situ generation from stable precursors that “mask” the NHC reactivity via reversible binding.
Red, Smith-Sweetser +4 more
core +2 more sources

