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Matrix Isolation Spectroscopy

1981
1. The history of matrix isolation spectroscopy..- Section A - Techniques.- 2. Infrared and Raman matrix isolation spectroscopy..- 3. Electronic spectroscopy of matrix isolated solutes..- 4. Magnetic circular dichroism - matrix isolation spectroscopy..- 5. Electron spin resonance studies of radicals trapped in rare-gas matrices..- 6.
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Metalloporphyrin photochemistry with matrix isolation

Journal of the American Chemical Society, 1991
The photochemistry of a number of metalloporphyrin oxoanion complexes has been examined by matrix isolation techniques, using both frozen solvent glasses and polymer films. After an extensive search for a noncoordinating, unreactive, glassing solvent, a 3: 1 mixture of 2,2-dimethylbutane and tert-butylbenzene was found to work well at temperatures ...
Kenneth S. Suslick   +2 more
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Oxidation of Matrix‐Isolated Silylenes

ChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Wolfram Sander   +4 more
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Matrix Isolation of Chalcogeno Heterocumulenes

Sulfur reports, 1999
Abstract The application of matrix isolation techniques connected with quantum mechanical calculations on generation and structural elucidation of cumulenic compounds containing sulfur or oxygen has been reviewed. Experimental matrix IR and UV/VIS data for all known species of this class of substances have been summarized together with some matrix ...
Günther Maier   +2 more
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FT-IR Matrix Isolation Studies

1980
Matrix isolation is a technique for trapping isolated molecules of the species to be studied in a large excess of an inert material by rapid condensation at a low temperature, so that the diluent forms a rigid cage or matrix. At a sufficiently low temperature, diffusion of the solute species is prevented and thus reactive species may be stabilized for ...
A. J. Barnes, W. J. Orville-Thomas
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Matrix isolation spectroscopy

Analytical Chemistry, 1979
Ε. L. Wehry, Gleb Mamantov
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Nuclear Matrix Isolated from Plant Cells

1996
Residual nuclear matrices can be successfully obtained from isolated nuclei of different monocot and dicot plant species using either high ionic or low ionic extraction protocols. The protein composition of isolated nuclear matrices depends on the details of isolation protocols. They are stable and present in all cases, a tripartite organization with a
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The decomposition of benzenesulfonyl azide: a matrix isolation and computational study.

Physical Chemistry, Chemical Physics - PCCP, 2017
Guohai Deng   +6 more
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