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Matrix Isolation of Perfluorinated p-Benzyne
Angewandte Chemie - International Edition, 2001As the first isolated derivative of 1,4-didehydrobenzene, 1,4-didehydro-2,3,5,6-tetrafluorobenzene (1) was generated from 1,4-diiodotetrafluorobenzene (2) by photolysis at 254 nm in a neon matrix at 3 K. The 4-iodo-2,3,5,6-tetrafluorophenyl radical 3 is formed as an intermediate in this reaction.
Wolfram Sander, David A Hrovat
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Isolation and Characteristics of Matrix Vesicles
2013Mineralizing matrix vesicles (MVs) are extracellular organelles produced by chondrocytes, osteoblasts, and odontoblasts under physiological conditions and by vascular smooth muscle cells under pathological conditions. MVs are involved in the early stage of mineralization allowing calcium and phosphate to accumulate, and therefore providing an optimal ...
René, Buchet +3 more
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Matrix Effects in Matrix Isolation Infrared Spectroscopy
Applied Spectroscopy, 1989A major factor limiting extensive use of matrix isolation gas chromatography-Fourier transform infrared spectrometry is the incompatibility of matrix-isolated spectra with available vapor- or condensed-phase spectral data bases. Here, matrix and surface effects on matrix isolation infrared spectra of organic molecules are investigated. Use of xenon at −
S. Jagannathan +2 more
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Electrodialytic Ion Isolation for Matrix Removal
Analytical Chemistry, 2012We report a fully automated online sample pretreatment system for ionic analytes that extracts the ionic analytes from the sample and largely removes the nonionic sample matrix and can preconcentrate the analyte. Sample pretreatment is a key analytical process; conventional pretreatment is conducted in a difficult to automate batchwise manner.
Shin-Ichi, Ohira +5 more
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