Achieving Remarkable Mechanochromism and White-Light Emission with Thermally Activated Delayed Fluorescence through the Molecular Heredity Principle [PDF]
Achieving high contrast mechanochromism (Δλem,max > 100 nm) and white-light emission under mild conditions from a single compound with a simple structure is a great challenge.
Lu, P-Y. +13 more
core +3 more sources
A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism [PDF]
The epistatic double hydrogen bonds that arise from the presence of a pendant carboxy group in a gold isocyanide complex result in strong aurophilic interactions in a magenta-emitting polymorph. This is due to the lack of the typically antiparallel dimer
Ito, Hajime +3 more
core +1 more source
This review summarizes how even minor chemical modifications can be used to shape spiropyran photochromism. We highlight how substituents, strain, and heteroatoms tune absorption, stability, switching efficiency, and overall photochromic behaviour.
Gianni Pacella, Giuseppe Portale
wiley +1 more source
High‐pressure studies of the lead‐free hybrid organic–inorganic ferroelectric [N(C2H5)3CH3]FeCl4 demonstrate record low compressibility, establishing it as the least compressible molecular ferroelectric known. In situ diamond anvil cell experiments identify halide selection and inorganic sublattice tuning as key compressibility controls, advancing ...
Takeshi Nakagawa +11 more
wiley +1 more source
Luminescence Mechanochromism Induced by Cluster Isomerization [PDF]
International audienceLuminescent mechanochromic materials exhibiting reversible changes of their emissive properties in response to external mechanical forces are currently emerging as an important class of stimuli-responsive materials because of ...
Cordier, Marie +17 more
core +1 more source
Mechanochromic Suction Cups for Local Stress Detection in Soft Robotics
Advancements in smart soft materials are enhancing the capabilities of robotic manipulators in object interactions and complex tasks. Mechanochromic materials, acting as lightweight sensors, offer easily interpretable visual feedback for localized stress
Goffredo Giordano +7 more
doaj +1 more source
This review article presents a comprehensive and integrated overview of wearable optical sensors, systematically bridging advanced functional materials with fundamental optical sensing mechanisms. It further highlights their diverse applications across healthcare, fitness monitoring, environmental surveillance, and food safety.
Rituparna Duarah +8 more
wiley +1 more source
Mechanofluorochromism (MFC) of Donor–π–Acceptor (D–π–A)‐Type Fluorescent Dyes
Mechanofluorochromism (MFC) is a photophysical phenomenon that induces changes in fluorescent colors as well as colors of organic fluorescent dyes in the solid‐state by external mechanical stimuli. In this Personal Account, we offer an insight into the mechanism for the expression of MFC and present a direction in the molecular design toward creating D–
Yousuke Ooyama
wiley +1 more source
Luminescent mechanochromism of a chiral complex: distinct crystal structures and color changes of racemic and homochiral gold(I) isocyanide complexes with a binaphthyl moiety [PDF]
Luminescent mechanochromism of a chiral gold(I) complex is investigated. The racemic and homochiral forms of the gold(I) complex possess distinct crystal packing arrangements with different emission colors.
Ito, Hajime, Jin, Mingoo, Seki, Tomohiro
core +1 more source
Liquid Crystal Elastomers Under Confinement: A Review of Template‐Based Fabrication and Applications
Template‐assisted confinement offers powerful ways to control the alignment, structure, and function of liquid crystal elastomers. This review highlights several templating strategies and details how geometry and interfaces shape material responses.
Meng Zhang +7 more
wiley +1 more source

