A trimodal anode architecture spatially regulates silicon clusters within confined interstitial environments formed by graphite and contorted hexabenzocoronene. This confinement suppresses silicon aggregation and localized stress while enabling efficient Li‐ion transport, achieving high‐capacity, stable lithium‐ion batteries.
Jeongmi Joo +11 more
wiley +1 more source
Metal-Organic Framework as Contrast Agents for Magnetic Resonance Imaging. [PDF]
Wang W +5 more
europepmc +1 more source
Encapsulation of solid–liquid barocalorics (BC) within MOFs harnesses their colossal BC performance whilst allowing active control of BC properties through BC‐MOF interactions. ABSTRACT Barocaloric (BC) effects at liquid–vapor transitions in hydrofluorocarbons drive most commercial technologies used for heating and cooling in the heating, ventilation ...
Ming Zeng +8 more
wiley +1 more source
Molecular Insights Shaping the Design of Metal-Organic Framework-Based Electrolytes. [PDF]
He S +6 more
europepmc +1 more source
Photo‐Switchable Molecular Module Programming PET Biodegradation in Aquatic Environments
We address the plastic durability paradox by integrating an itaconic acid–derived pyrrolidone module into polymer backbones. Sunlight in water triggers Norrish Type I ring‐opening and hydrophilization, enabling rapid biodegradation into nontoxic minerals.
Mohammad Asif Ali +16 more
wiley +1 more source
Micelle-Assisted Encapsulation Strategy in Metal-Organic Framework Nanocontainers Enables Durable Corrosion Protection. [PDF]
Nugraha AS +4 more
europepmc +1 more source
Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie +7 more
wiley +1 more source
Metal-Organic Framework-Derived Electrode Materials for Electrochemical Energy Storage: Design Strategies and Applications. [PDF]
Lu Y, Yao J, Chen Z, Jin L, Su Y, Liu P.
europepmc +1 more source
Architecture‐Driven Functional Coupling in Vertically Aligned Nanocomposites
Vertically aligned nanocomposites define a growth‐engineered architecture in which vertical interfaces, strain fields, defect pathways, and phase connectivity are created simultaneously. This review shows how these architectural features couple ferroic, optical, ionic, electrochemical, and device responses, establishing design rules and open challenges
Md Shatil Islam‐Shanto +4 more
wiley +1 more source
Trapping a Metastable Node in an Amorphous Metal-Organic Framework. [PDF]
F Sapnik A +5 more
europepmc +1 more source

