Results 171 to 180 of about 170,938 (311)

Water‐Compatible SuFEx‐Active Diazonium Linchpin Platform for Rapid Modular Diversification and On‐DNA Functionalization

Advanced Functional Materials, EarlyView.
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong, Dong Hyeon Kim, Yujin Lim, Yongseok Kwon, Sangkyu Lee, Han Yong Bae   +5 more
wiley   +1 more source

Size-Dependent Spin Crossover and Bond Flexibility in Metal-Organic Framework Nanoparticles

Size reduction offers a synthetic route to tunable phase change behavior. Preparing materials as nanoparticles causes drastic modulations to critical temperatures (Tc), hysteresis widths, and the “sharpness” of first-order versus second-order phase ...
Carl, Brozek, Anastasia, Andreeva, Checkers, Marshall, Taichi, Nishiguchi, Satoshi, Horike, Kentaro, Kadota, Audrey, Davenport   +6 more
core   +1 more source

Direct synthesis of a semiconductive double-helical phosphorus allotrope in a metal-organic framework

Nature Communications
There remains much ambiguity regarding the structure of red phosphorus. We report the adsorption and photo-polymerisation of P4 molecules encapsulated in an indium(III)-based metal-organic framework to afford a double-helical chain composite comprising ...
Sergei A. Sapchenko, Rodion V. Belosludov, Inigo J. Vitoria-Irezabal, Ivan da Silva, Xi Chen, George F. S. Whitehead, John Maddock, Louise S. Natrajan, Meredydd Kippax-Jones, Dukula De Alwis Jayasinghe, Carlo Bawn, Daniil M. Polyukhov, Yinlin Chen, Vladimir P. Fedin, Sihai Yang, Martin Schröder   +15 more
doaj   +1 more source

Dynamic Interfacial Chemistry of Choline Chloride as Electrolyte Additive for Stable Zn‐Iodine Batteries

Advanced Functional Materials, EarlyView.
Choline chloride (ChCl) additive enables dynamic interface engineering in Zn‐I2 batteries by forming hydrophobic polyiodide complexes and a Zn‐stabilizing Ch+‐rich layer under electric field modulation. This dual‐function strategy suppresses iodine hydrolysis and dendrite formation, while optimizing Zn2+ solvation and transport for high‐efficiency ...
Xiaoyu Bi, Yuchuan Ren, Ao Yu, Linlin Yang, Ren He, Yapeng Cheng, Xingqi Chang, Xuan Lu, Yanting Xie, Qian Xue, Hu Yuan, Canhuang Li, Runzhou Huang, Jordi Jacas Biendicho, Chaoqi Zhang, Jian Shang, Andreu Cabot   +16 more
wiley   +1 more source

Blood Biomarkers and Surface‐Enhanced Raman Spectroscopy for Gout: A Comprehensive Review

Advanced Functional Materials, EarlyView.
Schematic illustrating gout disease progression from asymptomatic hyperuricemia to chronic tophaceous disease, highlighting the limitations of conventional imaging and biochemical diagnostics and the potential of engineered SERS platforms for ultrasensitive blood‐based detection of urate‐related biomarkers across disease stages, with the color gradient
Isuri Perera, Chiranjeevi Kanike, Appurva Tiwari, Hongyan Wu, Larry D. Unsworth, Ben Bin Xu, Xuehua Zhang   +6 more
wiley   +1 more source

A Holistic Stabilization of the Anode in Lithium‐Sulfur Batteries Through a Ternary Alloy Fusion

Advanced Functional Materials, EarlyView.
LiTeAl anodes fabricated through a scalable thermal fusion technique holistically addresses the stability issues faced by lithium‐metal anodes in lithium–sulfur batteries. Aluminum forming a skeletal network with lithium suppresses dendrite growth and enhances energy density, while tellurium forming a robust SEI facilitates Li+‐ion flow.
Akhil Shenoy, Arumugam Manthiram
wiley   +1 more source

Solution‐Processed Thin‐Film Transistors With Tunable Temporal Dynamics for Neuromorphic Computing

Advanced Functional Materials, EarlyView.
Solution‐processed CNT and CNT/P3HT ion‐gated transistors exhibit materials‐defined synaptic timescales: fast CNT devices for high‐frequency spiking and slow hybrid devices for temporal integration. Embedding these dynamics into coupled reservoir‐computing and spiking neural network simulations reveals that a Hybrid‐Reservoir / CNT‐SNN architecture ...
Kevin Schnittker, Haoyi Lin, Zahra Bahrami, Strahinja Marinkovic, Sung Hyun Lee, Joseph Andrews   +5 more
wiley   +1 more source

Stability of Zr-Based UiO-66 Metal–Organic Frameworks in Basic Solutions

Although Zr-based metal–organic frameworks (MOFs) exhibit robust chemical and physical stability in the presence of moisture and acidic conditions, their susceptibility to nucleophilic attacks from bases poses a critical challenge to their overall ...
Seungheon Cha, Haein Kim, Jun Yeong Kim, Isaac Choi, Min Kim, Houng Kang, Jiwon Kang, Dopil Kim   +7 more
core   +1 more source

Ultrasmall High‐Entropy Materials: Nanoscale Effects, Synthesis, and Mechanistic Insights

Advanced Functional Materials, EarlyView.
This review article focuses on sub‐10 nm high‐entropy materials that combine nanoscale design with complex compositions for next‐generation applications. ABSTRACT Ultrasmall high‐entropy nanomaterials (USHENMs, <10 nm) merge multicomponent chemistry with size‐dependent effects, forming a distinct class of materials with unprecedented properties.
Yueyue He, Wenbo Wang, Simon Schweidler, Yanjiao Ma, Ben Breitung, Torsten Brezesinski   +5 more
wiley   +1 more source

A Dual‐Functional Electrolyte Additive for Highly Reversible Zinc‐Ion Batteries

Advanced Functional Materials, EarlyView.
This study introduces tetrabutylammonium bromide (TBAB) as a dual‐function additive for aqueous zinc‐ion batteries. TBAB disrupts the hydrogen‐bond network of water while TBA+ adsorbs on Zn to improve interfacial wettability and regulate Zn2+ flux, resulting in suppressed dendrite growth and parasitic reactions. This synergy extended the lifespan of Zn|
Shirui Zhang, Shixun Wang, Jianen Zhang, Jun Liu, Jinfeng Xie, Wentao Tang, Li Guan, He Huang, Qi Xue, Chunyi Zhi   +9 more
wiley   +1 more source