Results 1 to 10 of about 22,800 (233)
Metal alkoxides: Models for metal oxides: Alkoxide ligands in early transition metal organometallic chemistry [PDF]
, 1990 An effort was made to compare and contrast the reactivity of trialkylsiloxide vs tert-butoxide supported dinuclear centers, and an initiative aimed at studying the syntheses of polynuclear hydridoalkoxides and their reactions has been implemented.
Indiana Univ., Bloomington, IN (United States)
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COORDINATION COMPLEXES OF METAL ALKOXIDES: PART II. METAL ALKOXIDE – ETHYLENEDIAMINE COMPLEXES [PDF]
Canadian Journal of Chemistry, 1962 Some complexes of titanium isopropoxide, titanium ethoxide, aluminum isopropoxide, tantalum isopropoxide, and zirconium isopropoxide with ethylenediamine (en) are described. Two complexes of titanium isopropoxide with ethylenediamine, i.e. Ti(OPri)4,en and Ti2(OPri)8,en, were established by cryoscopic, X-ray powder photograph, and phase rule studies ...
M. S. Bains, D. C. Bradley
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An unusual chiral-at-metal mechanism for BINOL-metal asymmetric catalysis [PDF]
Nature CommunicationsChiral binaphthols (BINOL)-metal combinations serve as powerful catalysts in asymmetric synthesis. Their chiral induction mode, however, typically relies on multifarious non-covalent interactions between the substrate and the BINOL ligand.
Zhenxing Li +8 more
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Heterobimetallic Uranium(V)-Alkali Metal Alkoxides: Expanding the Chemistry of f-Block Elements [PDF]
MoleculesHeterobimetallic uranium(V) alkoxides incorporating monovalent alkali metal counterions display remarkable structural versatility, dictated by the steric demands of the alkoxide ligands and the ionic radius of the alkali metal.
Andreas Lichtenberg +3 more
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Alkoxide-based precursors for direct drawing of metal oxide micro- and nanofibres
Science and Technology of Advanced Materials, 2011 The invention of electrospinning has solved the problem of producing micro- and nanoscaled metal oxide fibres in bulk quantities. However, until now no methods have been available for preparing a single nanofibre of a metal oxide.
Tanel Tätte, Medhat Hussainov, Madis Paalo, Marko Part, Rasmus Talviste, Valter Kiisk, Hugo Mändar, Kaija Põhako, Tõnis Pehk, Kaido Reivelt, Marco Natali, Jonas Gurauskis, Ants Lõhmus and Uno Mäeorg
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METAL OXIDE ALKOXIDE POLYMERS: PART IV. THE HYDROLYSIS OF SOME TANTALUM ALKOXIDES [PDF]
Canadian Journal of Chemistry, 1962 Ebulliometric studies on the hydrolysis of tantalum pentaalkoxides Ta(OR)5, where R = Me, Prn, Bun, and Bus, have furnished important data on the polymeric nature of tantalum oxide alkoxides. It is shown from the variation of number-average degrees of polymerization as a function of degree of hydrolysis that the polymers conform to certain structural ...
D. C. Bradley, H. Holloway
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Carbohydrate Polymer Technologies and Applications, 2021 Pyrolytic conversion of biomass stands as one of the most promising sustainable routes to carbon-based nanostructures, including carbon dots (CDs).
Nisrine Hammi +5 more
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Low temperature XPS of sensitive molecules: Titanium butoxide photoelectron spectra
Applied Surface Science Advances, 2023 XPS analysis of soft materials remains a challenging task, with sample degradation presenting itself across a wide range of different materials. Correct protocols when performing the experimental spectral acquisition will ensure minimal proliferation of ...
Mark A. Isaacs
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Oxides powder prepared from metal alkoxide.
Journal of the Society of Powder Technology, Japan, 1985 Osamu YAMAGUCHI, Kiyoshi SIMIZU
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