Magnetochemistry, 2019 Two ligands, 2,4-di-2-pyridyl-2,4-pentanediol (rD and mD), were employed to synthesize two Mn2 complexes, [Mn2(rD)2Br2] (1) and [Mn2(mD)2(H2O)2]Br2 (2). Compound 1 crystallized in a tetragonal space group, P41212, with a novel hamburger shaped structure.
En-Che Yang +6 more
doaj +1 more source
From Materials to Systems: Challenges and Solutions for Fast‐Charge/Discharge Na‐Ion Batteries
Advanced Energy Materials, EarlyView.This review systematically analyzes the key characteristics limiting the fast‐charge/discharge capability of Na‐ion batteries (SIBs) from a multi‐scale perspective encompassing electrode materials, the electrode‐electrolyte interface, and the system. Furthermore, it presents practical solution strategies for the fundamental issues arising at each scale,
Bonyoung Ku +5 more
wiley +1 more source
Characterization of the Active Site and Insight into the Binding Mode of the Anti-angiogenesis Agent Fumagillin to the Manganese(II)-Loaded Methionyl Aminopeptidase from \u3cem\u3eEscherichia coli\u3c/em\u3e [PDF]
, 2005 EPR spectra were recorded for methionine aminopeptidase from Escherichia coli (EcMetAP-I) samples (~2.5 mM) to which one and two equivalents of Mn(II) were added (the latter is referred to as [MnMn(EcMetAP-I)]).
Bennett, Brian +3 more
core +1 more source
Preparation of SiO2/ZrO2 ceramic nanocomposite coating on Aluminum alloys as metallic part of the photovoltaic cells and study its corrosion behavior. [PDF]
Environmental Energy and Economic Research, 2017 Nowadays due to water shortage, the use of air humidity as the sustainable solution has been considered by cities located in coastal zones; especially in warm and humid climate. However, the use of air humidity also has its own problems such as corrosion
Seyyed Behnam Abdollahi Boraei +2 more
doaj +1 more source
[Metal alkoxides---models for metal oxides: Alkoxide ligands in early transition metal organometallic chemistry]. Progress report [PDF]
, 1992 An effort was made to compare and contrast the reactivity of trialkylsiloxide vs tert-butoxide supported dinuclear centers, and an initiative aimed at studying the syntheses of polynuclear hydridoalkoxides and their reactions has been implemented.
openaire +2 more sources
Bonding Energetics in Alkaline Metal Alkoxides and Phenoxides
Chemistry – A European Journal, 2003 AbstractThe bonding energetics in a variety of alkaline metal, alkoxides and phenoxides, MOR, was investigated based on the corresponding enthalpies of formation in the crystalline state determined by reaction‐solution calorimetry. The results obtained at 298.15 K were as follows: ΔfH$\rm{_{m}^{\,o}}$ (MOR, cr)/kJ mol−1 = 382.7±1.4 (LiOC6H5), 513.6±2.5
Nunes, Paulo +4 more
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A comparative study of macroporous metal oxides synthesized via a unified approach [PDF]
, 2009 A variety of macroporous metal oxides was synthesized via a spontaneous self-assembly process in aqueous solution starting from organic alkoxide precursors under a common set of conditions to present a consistent set of data for evaluation of macropore ...
Hakim, Sikander +2 more
core +3 more sources
Giant, 2020 The synthesis of high-molecular-weight poly(ε-caprolactone)s (PCLs) with enhanced mechanical properties remains challenging. Here we demonstrate the heterogeneous catalysis for the ring-opening polymerization (ROP) of ε-caprolactone (ε-CL).
Zi-Heng Liu +5 more
doaj +1 more source
Advanced Materials Interfaces, 2023 Despite garnering so much research interest, the potential technological developments of perovskites are limited due to the instability of perovskites in polar solvents.
Pooja Aggarwal +2 more
doaj +1 more source
Modelling of Lewis-Acid Catalyzed Ring Opening of Oxanorbornenes in the Synthesis of Azaheterocyclic Phosphonates [PDF]
, 2010 Since the discovery of the biological activity of aminophosphonates, research started on the synthesis of more constraint azaheterocyclic phosphonates. We developed a route via an intramolecular Diels-Alder reaction towards α-aminophosphonates 1.
Claeys, Diederica +3 more
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