Arbuscular Mycorrhizal Fungi Inoculation and Different Phosphorus Fertilizer Levels Modulate Phosphorus Acquisition and Utilization Efficiency of Alfalfa (<i>Medicago sativa</i> L.) in Saline-Alkali Soil. [PDF]
Plants (Basel)Zhong S +9 more
europepmc +1 more source
Slowing Down Water: Enhanced and Cation‐responsive MRI Contrast
Angewandte Chemie, EarlyView.The controlled modification of mesoporous silica nanoparticle side walls with kosmotropic motifs supports an ability to reduce water diffusive mobility and dramatically increase MRI contrast to levels unprecedented for highly kinetically stable Gd‐DOTA configurations (both q = 1 and q = 0).
Connor M. Ellis +5 more
wiley +1 more source
Bifunctional Iminophosphorane Superbases Enable the Highly Enantioselective Sulfa-Michael Addition to Fully Substituted Cyclopropene Carboxylic Acid Derivatives. [PDF]
J Am Chem SocYuan K +4 more
europepmc +1 more source
Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles
Angewandte Chemie, EarlyView.We report the synthesis of UOS, UOSe, and US2 nanoparticles under colloidal conditions. The magnetic properties were measured of all three materials and compared to prior studies of UO2 nanoparticles. Nanoparticle phases were determined using powder diffraction, and size by transmission electron microscopy.
Cheyenne Orozco +7 more
wiley +1 more source
Machine learning guided discovery of water stable metal-organic frameworks for photocatalytic hydrogen production. [PDF]
Chem SciNiu X +5 more
europepmc +1 more source
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
Angewandte Chemie, EarlyView.The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti +9 more
wiley +1 more source
Photochemistry of iron-containing secondary organic aerosol is impacted by relative humidity during formation. [PDF]
NPJ Clim Atmos SciGarner NM +9 more
europepmc +1 more source
Angewandte Chemie, EarlyView.A decoupled cycling architecture along with cost‐effective membrane and efficient catalyst is developed for asymmetric zinc‐air battery. The decoupled design ensures stable operation of catalyst and the pH‐dynamic influence on battery performance is explored, which provides paths for efficient utilization of pH‐decoupling electrolytes.
Yeshu Tan +6 more
wiley +1 more source
IAA was involved in phosphorus deficiency-induced cluster roots formation in Macadamia integrifolia. [PDF]
Sci RepPan H +7 more
europepmc +1 more source
Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes
Angewandte Chemie, EarlyView.A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi +7 more
wiley +1 more source