Results 181 to 190 of about 8,724 (213)

Synthesis, Structures and Corrosion Inhibition Properties of 4-Nitrophenylacetato-Rare-Earth(III) 1D Coordination Polymers. [PDF]

Molecules
Neill JM, Salpadoru Thuppahige NY, Guo Z, Deacon GB, Junk PC.   +4 more
europepmc   +1 more source

Dual Activation of H2 and CO2 by a Pincer‐Type Ni–Zn Heterobimetallic Complex

Angewandte Chemie, EarlyView.
A bimetallic Ni−Zn complex performs sequential activations of H2 (1 equiv) and CO2 (2 equiv). This bimetallic cooperativity is attributed to the weak Lewis acidic nature of Zn(II), which promotes fluxional ligand binding. Namely, an X‐type ligand at Ni, where X is hydride or formate, toggles between two different binding modes: bridging Zn(μ‐X)Ni and ...
Krishnendu Dey, Matthias Borowski, Gregor Schnakenburg, Connie C. Lu   +3 more
wiley   +1 more source

Unbiased Structure Prediction of Sophisticated Cage Structures

Angewandte Chemie, EarlyView.
We introduce the software and workflow for automated, unbiased exploration of all possible connectivities of a given set of building blocks and their stoichiometry to predict stable cage structures. ABSTRACT Cage structure prediction has made significant strides by generating structures based on what the community has seen before.
Andrew Tarzia, Giovanni M. Pavan
wiley   +1 more source

Hydrophilic or Hydrophobic? How Byproducts Change the Water Affinity of Fischer-Tropsch Catalysts. [PDF]

JACS Au
Sengupta S, Klaver AJ, Zheng Q, de Jong M, Voeten RLC, Gladden LF, Bezemer GL.   +6 more
europepmc   +1 more source

Defect‐Guided Assembly of Aperiodic and Flexible Metal–Organic Frameworks From Pre‐Formed Cages

Angewandte Chemie, EarlyView.
A cage‐directed strategy is used to program topologically correlated defects and induce aperiodicity in HKUST‐1‐type MOFs. A missing carboxylate group in the linker drives the formation of Cu‐vacancy domains, while Rh(II) cages spatially confine these defects.
Francisco Sánchez‐Férez, Akim Khobotov‐Bakishev, Borja Ortín‐Rubio, Cornelia von Baeckman, Laura Hernández‐López, Alba Cortés‐Martínez, Robert A. I. Paraoan, Roberto Boada, Judith Juanhuix, Felipe Gándara, Andrew L. Goodwin, Arnau Carné‐Sánchez, Daniel Maspoch   +12 more
wiley   +1 more source

<i>Remote</i>-Markovnikov Hydrobromination and Hydrochlorination of Allyl Carboxylates via Dual Photoredox/Cobalt Catalysis. [PDF]

J Am Chem Soc
Khosravi A, Zhang Y, Zhao G, Radefeld KJ, Sharma S, Pannilawithana NA, Zhang Y, Liu P, Ngai MY.   +8 more
europepmc   +1 more source

Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates

Angewandte Chemie, EarlyView.
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey, Gary S. Nichol, Stephen P. Thomas, Dominic R. Willcox, Michael. J. Ingleson   +4 more
wiley   +1 more source

Enabling Moisture and Interfacial Stability in Sulfide Solid Electrolytes via a Processable Organic Coating Strategy for High‐Voltage All‐Solid‐State Batteries

Angewandte Chemie, EarlyView.
The solid electrolyte, argyrodite (Li6PS5Cl or LPSCl), “waxed” with a 25 nm coating of decanoic acid (DA; C10H19O2) is protected against hydrolysis at high relative humidity and maintains its ionic conductivity. DA–LPSCl exhibits enhanced stability at both NCM|DA–LPSCl and Li|DA–LPSCl interfaces: solid state batteries with a bare NCM85 cathode and Li ...
Lanting Qian, Cameron Dean, Ivan Kochetkov, Hengning Chen, Yangyang Huang, Linda Nazar   +5 more
wiley   +1 more source

Bismuth Bicycles. [PDF]

J Pept Sci
Voss S, Sagar A, Tiberghien A, Hughes RJL, Chen L, Rioja I, Frigerio M, Skynner MJ, Spring DR.   +8 more
europepmc   +1 more source

Evaluating metal-organic precursors for focused ion beam-induced deposition through solid-layer decomposition analysis. [PDF]

Beilstein J Nanotechnol
Jany BR, Madajska K, Butrymowicz-Kubiak A, Krok F, Szymańska IB.   +4 more
europepmc   +1 more source