Results 31 to 40 of about 3,163,959 (346)

Towards a new method for coating heritage lead [PDF]

open access: yes, 2014
Ethanolic solutions of long-chain carboxylic acids can be applied to lead metal substrates to form a coating of lead carboxylate which provides protection against atmospheric pollutants.
Adriaens, Mieke   +5 more
core   +2 more sources

Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

open access: yesInorganics, 2023
Two new coordination polymers based on Zn(II) and 2,5-diiodoterephthalate—{[Zn(2,5-I-bdc)bpe}] (1) and {[Zn(2,5-I-bdc)bpen}] (2)—were synthesized and characterized.
Alexander S. Zaguzin   +4 more
doaj   +1 more source

Carboxylic acid-modified metal oxide catalyst for selectivity-tunable aerobic ammoxidation

open access: yesNature Communications, 2018
Precisely controlling the surface properties of base-metal oxide catalysts to tune the reaction selectivity remains a challenge. Here, the authors show that a green modification of manganese oxide surface with carboxylates can be used to tune the ...
Xiuquan Jia   +5 more
doaj   +1 more source

Site-selective electrochemical carboxylation of aromatic C(sp2)–H bonds with CO2

open access: yesCurrent Research in Green and Sustainable Chemistry, 2023
We present a facile and economical method for synthesizing aromatic carboxylic acid derivatives through direct electrochemical C(sp2)–H carboxylation of (hetero)arenes with CO2.
Rong Zhao   +4 more
doaj   +1 more source

Directed assembly via selectively positioned host functionality [PDF]

open access: yes, 2013
Introduction of distal carboxylic acid groups over two positions at the upper-rim of a di-O-alkylcalix[4]arene provides facile control over coordination polymer or discrete metal-organic capsule formation.
Beavers, Christine M   +3 more
core   +1 more source

Theories and experimental investigations of the structural and thermotropic mesomorphic phase behaviors of metal carboxylates

open access: yesApplied Petrochemical Research, 2014
Investigations on the phase behaviors and structural properties of mono-, di- and poly-valent metal carboxylates are reviewed with reference to developments in experimental and theoretical concepts surrounding their liquid crystalline properties.
P. Nelson, Richard A. Taylor
semanticscholar   +1 more source

Two-step analytical procedure for the characterization and quantification of metal soaps and resinates in paint samples

open access: yesHeritage Science, 2018
Metal soaps and resinates are known to be spontaneously formed in artistic paintings, as a product of the reaction between aliphatic and terpenoid acids released by hydrolysis and oxidation of the organic media and certain cations contained in some ...
Jacopo La Nasa   +3 more
doaj   +1 more source

Unravelling the surface chemistry of metal oxide nanocrystals, the role of acids and bases [PDF]

open access: yes, 2014
We synthesized HfO2 nanocrystals from HfCl4 using a surfactant-free solvothermal process in benzyl alcohol and found that the resulting nanocrystals could be transferred to nonpolar media using a mixture of carboxylic acids and amines.
De Keukeleere, Katrien   +5 more
core   +1 more source

Solvent induced rapid modulation of micro/nano structures of metal carboxylates coordination polymers: mechanism and morphology dependent magnetism

open access: yesScientific Reports, 2014
Rational modulation of morphology is very important for functional coordination polymers (CPs) micro/nanostructures and new strategies are still desired to achieve this challenging target.
Kun Liu   +7 more
semanticscholar   +1 more source

Selective reduction and homologation of carbon monoxide by organometallic iron complexes

open access: yesNature Communications, 2018
Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and ...
Helen R. Sharpe   +10 more
doaj   +1 more source

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