Results 51 to 60 of about 1,843,878 (304)
The aim of this work is to introduce a novel statistical technique for quantifying the concentration field uniformity of the liquid-liquid mixing process within a micro-scale chaotic pipeline. For illustration, the microscale liquid-liquid mixer in which
Haotian Wang +4 more
doaj +1 more source
A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion [PDF]
A helping hand: Incorporation of Group 2 Lewis acids into a macrocycle appended to a phosphine ligand attached to a rhenium carbonyl complex promotes otherwise unfavorable transformations of coordinated CO (see scheme; M=Ca, Sr).
Bercaw, John E. +2 more
core +1 more source
Oligocyclopentadienyl Transition Metal Complexes [PDF]
Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.
de Azevedo, Cristina G. +1 more
openaire +2 more sources
Calpain small subunit homodimerization is robust and calcium‐independent
Calpains dimerize via penta‐EF‐hand (PEF) domains. Using single‐molecule force spectroscopy, we measured the strength and kinetics of PEF–PEF homodimer binding. The interaction is robust, shows a transient conformational step before dissociation, and remains largely insensitive to Ca2+.
Nesha May O. Andoy +4 more
wiley +1 more source
Microwave heating has been applied in the field of drying rare earth carbonates to improve drying efficiency and reduce energy consumption. The effects of power density, material thickness and drying time on the weight reduction (WR) are studied using ...
Yin Shaohua +4 more
doaj +1 more source
In this work, a visualization experiment for rectangular channels was carried out to explore gas–liquid two-phase flow characteristics. Typical flow patterns, including bubble, elastic and mixed flows, were captured by direct imaging technology and the ...
Kai Yang +4 more
doaj +1 more source
Experimental and theoretical characterization of the Zn - Zn bond in [Zn2(η5-C5Me5)2] [PDF]
The existence and characterization of a bond between the Zn atoms in the recently synthesized complex [Zn2(5-C5Me5)2], as well as between Zn and ligand C atoms is firmly based on neutron diffraction and low-temperature X-ray synchrotron diffraction ...
Carmona Guzmán, Ernesto +9 more
core +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source
Reclamation with Recovery of Radionuclides and Toxic Metals from Contaminated Materials, Soils, and Wastes [PDF]
A process has been developed at Brookhaven National Laboratory (BNL) for the removal of metals and radionuclides from contaminated materials, soils, and waste sites. In this process, citric acid, a naturally occurring organic complexing agent, is used to
Dodge, C. J., Francis, A. J.
core +1 more source
This study reveals a unique active site enriched in methionine residues and demonstrates that these residues play a critical role by stabilizing carbocation intermediates through novel sulfur–cation interactions. Structure‐guided mutagenesis further revealed variants with significantly altered product profiles, enhancing pseudopterosin formation. These
Marion Ringel +13 more
wiley +1 more source

