Results 91 to 100 of about 309,328 (314)

Metal complexes of ethylenetetrathioglycollic acid and related ligands [PDF]

open access: yes
The purpose of this work has been primarily the investigation of the complexes formed by etnylenetetrathioglycollic acid with Co(II), Ni (II), Cu (II) and Zn (II). This ligand has some similarities to themuch-studied ethylenediaminetetraacetic aoid.
Malcolm, Donna Evelyn
core  

Understanding the cellular behaviour of the luminescent lanthanide complexes [PDF]

open access: yes, 2009
The design of responsive optical cellular probes remains a key challenge for biology and medicine. Luminescent lanthanide complexes are well suited for this purpose, with their information-rich emission profiles, and long luminescence lifetimes which ...
New, Elizabeth Joy
core  

Fundamental Studies of Early Transition Metal-Ligand Multiple Bonds: Structure, Electronics, and Catalysis [PDF]

open access: yes, 2011
Two major topics are covered: the first section is focused on the structure, electronics, stoichiometric reactivity and catalysis of nonmetallocene early transition metal complexes that often contain metal-ligand multiple bonds (Chapters 2-4); the second
Ian Albert Tonks, Tonks, Ian Albert
core   +1 more source

Metal-metal bond lengths in complexes of transition metals [PDF]

open access: yesProceedings of the National Academy of Sciences, 1976
In complexes of the transition metals containing clusters of metal atoms the cobalt-cobalt bond lengths are almost always within 1 pm of the single-bond value 246 pm given by the enneacovalent radius of cobalt, whereas most of the observed iron-iron bond lengths are significantly larger than the single-bond value 248 pm, the mean being 264
openaire   +2 more sources

Carboxylic‐Acid Functionalized Multiwalled Carbon Nanotube‐Alkane‐Based Resistive Temperature Sensor for Cold Chain Applications

open access: yesAdvanced Engineering Materials, EarlyView.
This study presents a reversible temperature sensor with high switching ratio, ∼103. The device is fabricated using PET‐ITO and carbon nanotube dispersions in alkane. Considering its application in cold chain logistics, a proof‐of‐concept with LED is showcased. Thus, a temperature drop below the threshold temperature (crystallization temperature of the
Sunil Kumar Behera   +8 more
wiley   +1 more source

Low‐Cost, Large‐Scale Nanoporous Metals by Mechanical Alloying, Oxide Reduction, and Dealloying of Powders

open access: yesAdvanced Engineering Materials, EarlyView.
Powder metal processing provides scalable advantages in nanoporous (np) metal development. Mechanical alloying is used to produce unique precursors for hybrid nanopore formation by oxide reduction and dealloying. As demonstrated in np Ag, this approach improves process efficiency while promoting smaller ligaments and larger pores, both of which are ...
Mark A. Atwater, Oliver A. Fowler
wiley   +1 more source

Coordination chemistry of metal surfaces and metal complexes [PDF]

open access: yesPure and Applied Chemistry, 1980
The coordination chemistry of two isomeric molecules, acetonitrile and methyl isocyanide, has been characterized for (A) single crystal nickel surfaces as a function of crystallography and surface composition, (B) nickel catalyst surfaces and (C) molecular mononuclear and polynuclear metal complexes.
openaire   +2 more sources

What Do Large Language Models Know About Materials?

open access: yesAdvanced Engineering Materials, EarlyView.
If large language models (LLMs) are to be used inside the material discovery and engineering process, they must be benchmarked for the accurateness of intrinsic material knowledge. The current work introduces 1) a reasoning process through the processing–structure–property–performance chain and 2) a tool for benchmarking knowledge of LLMs concerning ...
Adrian Ehrenhofer   +2 more
wiley   +1 more source

Reaction of Pentadienyl Complexes with Metal Carbonyls:  Synthetic, Structural, and Theoretical Studies of Metallabenzene π-Complexes

open access: yes, 2016
The reaction of open and half-open sandwich complexes of iron and ruthenium with metal carbonyls was studied. Three types of complexes could be isolated:  Carbonyl-bridged iron−ruthenium dimers with cyclopentadienyl and pentadienyl terminal ligands ...
Frank Podewils (3077331)   +5 more
core   +1 more source

Organometallic iridium(III) anticancer complexes with new mechanisms of action: NCI-60 screening, mitochondrial targeting, and apoptosis [PDF]

open access: yes, 2013
Platinum complexes related to cisplatin, cis-[PtCl2(NH3)2], are successful anticancer drugs; however, other transition metal complexes offer potential for combating cisplatin resistance, decreasing side effects, and widening the spectrum of activity ...
Hands-Portman, Ian   +5 more
core   +1 more source

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