Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies [PDF]
This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination
Barry, Nicolas P. E., Sadler, P. J.
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Die Kinetik typischer Hydrolysereaktionen von mehrwertigen Kationen
This review summarizes kinetic investigations concerning the homogeneous hydrolysis reactions of multivalent metal cations in aqueous solution. - Three main types of reactions are discussed : a) Protolysis of aquated cations to form mononuclear metal-
Hartmut Wendt
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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(II) [PDF]
Monometallic complexes based on 3d transition metal ions in certain axial coordination environments can exhibit appreciably enhanced magnetic anisotropy, important for memory applications, due to stabilisation of an unquenched orbital moment.
Bhasaran, Lakshmi +6 more
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Grinding efficiency improvement of hydraulic cylinders parts for mining equipment
The aim of the article is to find out ways to improve parts treatment and components of mining equipment on the example of hydraulic cylinders parts, used as pillars for mine roof supports, and other actuator mechanisms.
Korotkov Aleksandr +4 more
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Novel Preparation of Co(II), Ni(II), Cu(II), and Zn(II) metal complexes was synthesized by the regular reflux method, and the nano-particles were prepared by using the thermal decomposition method.
Usan Pathinathan Saleth Prabhakar
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Versatile Coordination of Cyclopentadienyl-Arene Ligands and Its Role in Titanium-Catalyzed Ethylene Trimerization [PDF]
Cationic titanium(IV) complexes with ansa-(η5-cyclopentadienyl,η6-arene) ligands were synthesized and characterized by X-ray crystallography. The strength of the metal-arene interaction in these systems was studied by variable-temperature NMR ...
Adams J. R. +108 more
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Synthesis, Characterization and Antimicrobial Activities of Some Nicotinamide – metal Complexes
Some transition metal complexes of nicotinamide have been prepared and characterized using melting point, conductivity measurement, infrared, electronic, HNMR and atomic absorption spectroscopic methods. . The antibacterial and antifungal studies of the
A Lawal +5 more
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Synthesis and characterization of a new N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions.
Dilip C. Sawant +2 more
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Metal-only Lewis pairs between group 10 metals and Tl(I) or Ag(I): insights into the electronic consequences of Z-type ligand binding† [PDF]
Complexes bearing electron rich transition metal centers, especially those displaying coordinative unsaturation, are well-suited to form reverse-dative σ-interactions with Lewis acids.
Barnett, Brandon R. +6 more
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The application of HP-GFC chromatographic method for the analysis of oligosaccharides in bioactive complexes [PDF]
The aim of this work was to optimize a GFC method for the analysis of bioactive metal (Cu, Co and Fe) complexes with olygosaccharides (dextran and pullulan). Bioactive metal complexes with olygosaccharides were synthesized by original procedure.
Savić Ivan +3 more
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