Der bimetallische M14‐Cluster [Co3Ga2]H(μ2‐GaTMP)9 wurde durch einen ko‐reduktiven Ansatz erzielt. Dieser Ansatz nutzt Mg und H2, um den Ga‐TMP‐Liganden selektiv zu entschützen und das TMP abzufangen, was zur Bildung eines gemischtmetallischen Co/Ga Clusterkerns führt, was diesen zu einem strukturellen Vertreter eines vergleichbaren Gegenstücks der ...
Fabrizio E. Napoli +6 more
wiley +1 more source
Stability and electronic structure of the complex K$_2$PtCl$_6$ structure-type hydrides
The stability and bonding of the ternary complex K$_2$PtCl$_6$ structure hydrides is discussed using first principles density functional calculations.
D. J. Singh +11 more
core +1 more source
Regio‐ and enantioselective nickel-alkyl catalyzed hydroalkylation of alkynes
The migratory insertion of metal-hydride into alkene has allowed regioselective access to organometallics, readily participating in subsequent functionalization as one conventional pathway of hydroalkylation, whereas analogous process with feedstock ...
Qian Gao +7 more
doaj +1 more source
Search for superconducting icosahedral hydrides via coordination number engineering
Superconducting hydrides provides a possible route to hunt for high-temperature superconductors. Recent high-throughput calculations suggest hydrides, which are combined by alkali or alkali-earth elements and hydrogen-and-transition-metal units, as ...
Hao Song +4 more
doaj +1 more source
CO2 reduction with protons and electrons at a boron-based reaction center. [PDF]
Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparation of
Essex, Laura A +3 more
core
First case of nickel-metal hydride battery ingestion in child. [PDF]
Hui ML, Ng JH.
europepmc +1 more source
Chemical Structure Comparison via Scanning Electron Microscopy of Spent Commercial Nickel-Metal Hydride Batteries. [PDF]
Walther T.
europepmc +1 more source
Characterisation of paraffin-based hybrid rocket fuels loaded with nano-additives
In this work, a new composition based on Paraffin wax and HTPB fuel, loaded with nanoparticles has been proposed for hybrid propulsion system. Lithium aluminium hydride (LiAlH4) and Magnesium hydride (MgH2) nanoparticles have been used as additives.
Md. Zishan Akhter, M. A. Hassan
doaj +1 more source
Measurement and the improvement of effective thermal conductivity for a metal hydride bed - a review. [PDF]
Ye J, Li Z, Zhang L, Wang S, Jiang L.
europepmc +1 more source
Kinetic, Spectroscopic, and X-Ray Crystallographic Evidence for the Cooperative Mechanism of the Hydration of Nitriles Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo Complex [PDF]
The tetranuclear ruthenium-oxo-hydroxo-hydride complex {[(PCy3)(CO)RuH]4(μ4-O)(μ3-OH)(μ2-OH)} (1) was found to be a highly cooperative catalyst for the nitrile hydration reaction. The cooperative mechanism of the hydration of benzonitrile was established
Lindeman, Sergey V. +2 more
core +1 more source

