Results 101 to 110 of about 12,074 (248)

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

Angewandte Chemie, EarlyView.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa, Riccardo Bellin, Besma Boulila, Francesco Vaghi, Manuel Orlandi   +4 more
wiley   +2 more sources

Spectroscopic investigations under whole cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

, 2020
Hydrogenases are among the fastest H2 evolving catalysts known to date and have been extensively studied under in vitro conditions. Here, we report the first mechanistic investigation of an [FeFe]-hydrogenase under in vivo conditions.
Holly J., Redman, Joachim, Heberle, Moritz, Senger, Pierre, Ceccaldi, Emanuel, Pfitzner, Marco, Lorenzi, Lívia S., Mészáros, Sven T., Stripp, Gustav, Berggren   +8 more
core   +1 more source

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +2 more sources

Anisotropic thermal conductivity and permeability of compacted expanded natural graphite [PDF]

, 2010
The anisotropic thermal conductivities and permeabilities are investigated for discs and plates of compacted expanded natural graphite. The measuring directions of heat conductivity and permeability are both parallel and perpendicular to the pressing ...
Tamainot-Telto, Zacharie, Wang, L. W., Wang, R. Z., Critoph, Robert E., Metcalf, Steven J.   +4 more
core   +1 more source

Study of change in packed bed state of nano-structured FeTi hydrogen storage alloy

Nihon Kikai Gakkai ronbunshu, 2019
The volume of metal hydride packed bed changed by the influence of the expansion during hydrogen absorption and by the contraction during hydrogen desorption was measured by direct observation. The metal hydride used in the experiment are newly developed
Masahiro MATSUSHITA, Ikko TAJIMA, Masatake ABE, Hideki TOKUYAMA   +3 more
doaj   +1 more source

Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character

Angewandte Chemie, EarlyView.
Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge, Emeric Schubert, Israel Fernández, Terrance J. Hadlington   +3 more
wiley   +2 more sources

Metal hydride compacts of improved thermal conductivity

, 2019
Metal hydrides begin as hydride-forming metal alloys with good thermal conductivity. However, undergoing hydriding/dehydriding reactions and subsequently causing large strain changes, they decrepitate and finally form a powder bed.
Kim, KJ, Razani, A, Montoya, B, Lee, KH
core   +1 more source

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

Angewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai, Yalei Zhang, Yue Zhao, Shujun Li, Nana Ma, Qingchun Xia, Yiwei Liu, Rongji Liu, Shuxia Liu, Xuenian Chen, Carsten Streb   +10 more
wiley   +2 more sources

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang, Irena Efremenko, Thiyagarajan Subramanian, Amit Kumar, Liat Avram, Yael Diskin‐Posner, David Milstein   +6 more
wiley   +2 more sources

Comparative analysis of single and paired metal hydrides based thermal energy storage system

Case Studies in Thermal Engineering
This study aims to determine which thermal energy storage (TES) system is most suited for a concentrated solar power (CSP) plant. The question is which the best TES system, whether utilizing a single metal hydride or employing dual metal hydrides with or
Sofiene Mellouli, Faouzi Askri, Talal Alqahtani, Salem Algarni, Badr M. Alshammari, Lioua Kolsi   +5 more
doaj   +1 more source