Results 81 to 90 of about 12,074 (248)

Catalytic Enantioselective Multicomponent Reactions of Sulfoxonium Ylides Enabled by a Formal Rearrangement—A Versatile Entry to Enantioenriched α‐Sulfanyl Carbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli   +10 more
wiley   +2 more sources

Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun   +6 more
wiley   +1 more source

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth

open access: yesAngewandte Chemie, EarlyView.
Driven by the mechanistic debate of Bi‐catalyzed CO2‐to‐HCOOH conversion, ambiguity remains regarding true reaction pathways. To resolve this, we combined constant‐potential AIMD simulations with spectroscopic evidence to analyze the competitive pathways.
Hyun Dong Jung   +4 more
wiley   +2 more sources

Sulfide‐Based Electrolytes for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review covers the structural features and synthesis strategies of sulfide‐based solid electrolytes, as well as critical challenges related to conductivity, interfacial and moisture stability, and scaling‐up for practical application in Sodium‐based All Solid‐State Batteries.
Han Yang   +6 more
wiley   +1 more source

Desenvolvimento de método HG-ICP OES para determinação simultânea de arsênio e selênio [PDF]

open access: yes, 2014
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro Tecnológico, Programa de Pós-Graduação em Engenharia Química, Florianópolis, 2014No presente trabalho são descritas as etapas de desenvolvimento eimplantação de uma rotina analítica ...
Zappelini, Aline Iara
core  

Redirecting a Native Ene‐Reductase Toward Desaturation With Reverse Enantioselectivity

open access: yesAngewandte Chemie, EarlyView.
A native ene‐reductase, XenA, was repurposed to catalyze the reverse‐enantioselective desaturation of cyclohexanones. The final variant was obtained through extensive protein engineering, combining PROSS‐guided computational design with mutagenesis and screening.
Qing‐Qing Zeng   +4 more
wiley   +2 more sources

Recent progress in atomically precise Ag/Cu-based hydride clusters

open access: yesPolyoxometalates
Owing to advantages in synthesis, separation, structure determination, and low cost (compared to noble metal nanoclusters), Ag/Cu hydride clusters (and their alloys) have received increasing research interest in recent decades and have shown great ...
Ying Lv   +4 more
doaj   +1 more source

Metal Hydride Technology* [PDF]

open access: yesZeitschrift für Physikalische Chemie, 1979
A promising alternative for hydrogen storage is storage as a metal hydride. The properties and applications of those systems which have proven or potential utility as hydrogen storage compounds are summarized. Specific systems discussed are magnesium alloy hydrides, iron-titanium alloys, titanium-chromium alloys, and rare earth alloys. (LK)
openaire   +1 more source

Synthesis of functionalized polyolefins in a new continuous bench‐scale reactor apparatus

open access: yesAIChE Journal, EarlyView.
Abstract In‐reactor functionalized polyolefins (FPOs), produced by molecular catalysts, are a new class of polymer materials with applications ranging from high performance adhesives to bitumen compatibilization. In this work, we disclose a procedure for the synthesis of FPOs in a new Continuous Bench‐scale Reactor Apparatus (COBRA).
Miloud Bouyahyi   +7 more
wiley   +1 more source

Multistage metal hydride compressor [PDF]

open access: yes, 1986
Metal hydride compressors can compress hydrogen to high pressures without using mechanical moving parts. They are particularly suited for tritium applications because they require minimal maintenance.
Heung, L.K.
core  

Home - About - Disclaimer - Privacy