Results 71 to 80 of about 35,023 (278)

Technical and economic aspects of hydrogen storage in metal hydrides [PDF]

open access: yes
The recovery of hydrogen from such metal hydrides as LiH, MgH2, TiH2, CaH2 and FeTiH compounds is studied, with the aim of evaluating the viability of the technique for the storage of hydrogen fuel.
Schmitt, R.
core   +1 more source

Nuclear Spin‐Free 70Ge/28Si70Ge Quantum Well Heterostructures Grown on Industrial SiGe‐Buffered Wafers

open access: yesAdvanced Science, EarlyView.
Hyperfine coupling to 29Si$^{29}{\rm Si}$ and 73Ge$^{73}{\rm Ge}$ nuclear spins limits hole spin‐qubit coherence in Ge heterostructures. We demonstrate device‐grade, nuclear‐spin‐free 70Ge$^{70}{\rm Ge}$/28Si70Ge$^{28}{\rm Si}^{70}{\rm Ge}$ quantum wells grown on industrial SiGe buffers with minimal use of enriched precursors.
Patrick Daoust   +11 more
wiley   +1 more source

A Comprehensive Review on Hydrogen Absorption Behaviour of Metal Alloys Prepared through Mechanical Alloying

open access: yesMetals, 2020
Hydride-forming alloys are currently considered reliable and suitable hydrogen storage materials because of their relatively high volumetric densities, and reversible H2 absorption/desorption kinetics, with high storage capacity.
Thabang Ronny Somo   +5 more
doaj   +1 more source

Energy‐Resolved Femtosecond Dynamics of Plasmon‐Induced Hole Injection at Au/GaN Heterointerfaces

open access: yesAdvanced Science, EarlyView.
We reveal the spectral signature of ultrafast nonthermal hot‐hole transfer at plasmonic heterointerfaces, which reshapes hot‐carrier relaxation dynamics and significantly enhances hydrogen evolution, providing a mechanistic basis for optimizing hot‐carrier utilization in photocatalysis.
Yuying Gao   +8 more
wiley   +1 more source

The Far Side of Carboranes: Anticancer Active Monocations and Ambiently Stable Dications

open access: yesAngewandte Chemie, EarlyView.
This work describes the synthesis of bench‐stable dicationic carboranes. Their enhanced electrophilicity is documented by opening the clusters with weak nucleophiles or dihydrogen. The surprising stability of positively charged carboranes in water enabled a study of their in vitro antiproliferative activity, which surpassed the effects of doxorubicin ...
Vlastimil Němec   +10 more
wiley   +2 more sources

Unraveling Hydride‐Driven Multiphasic Reduction Toward Tunable Germanium Structures for Lithium‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
The sodium hydride (NaH)‐mediated reduction of germanium dioxide yields distinct Ge structures depending on the amount of reductant, revealing the dual roles of NaH in the reduction pathways. The synthesized Ge under off‐stoichiometric conditions exhibits a porous morphology and reduced crystallinity, which effectively mitigates volume expansion during
Gijung Lee   +12 more
wiley   +1 more source

Hyperpolarization of Molecular Deuterium

open access: yesAngewandte Chemie, EarlyView.
Hyperpolarized molecular deuterium is generated and detected using a nonhydrogenative SABRE catalyst with nicotinamide. The resonance shows a strongly enhanced partially negative line, substrate‐dependent and sensitive to transient intermediates.
Theresa L. K. Hune   +5 more
wiley   +2 more sources

Functional Materials Based on Metal Hydrides

open access: yesInorganics, 2018
Storage of renewable energy remains a key obstacle for the implementation of a carbon free energy system. There is an urgent need to develop a variety of energy storage systems with varying performance, covering both long-term/large-scale and high ...
Hai-Wen Li   +3 more
doaj   +1 more source

Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light

open access: yesAdvanced Science, EarlyView.
A novel photo‐induced methodology for hydrocarbonylation has been established, resolving the inherent conflicts between competitive olefin and CO insertion in traditional methods that necessitate harsh conditions. Accordingly, an efficient and versatile hydrocarbonylation of olefins enabled by visible‐light irradiation under ambient conditions has been
Hongchi Liu, Tianze Zhang, Hanmin Huang
wiley   +1 more source

Toward Predictive Theory in Single‐Atom Catalysis

open access: yesAdvanced Science, EarlyView.
A lifecycle‐oriented framework reframes modeling in single‐atom catalysis. By combining ensemble‐based descriptions with explicit validation against experimental observables, the approach defines the scope of theory across catalyst synthesis, activity, stability, and safety, clarifying where quantitative insight is possible and where interpretation ...
Andrea Ruiz‐Ferrando   +3 more
wiley   +1 more source

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