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Spectroscopic and Reactivity Studies of a Copper‐Containing Metallacrown
Angewandte Chemie International Edition in English, 1994Cu and Cu3Mg‐containing complexes form when the metallacrown 1 is treated with lead or magnesium nitrate, respectively. In the first reaction the sodium ion in the cavity formed by the six copper atoms of the macrocyclic host is replaced by a copper ion, which suggests the destruction of the structure of the macrocycle. In the replacement of the sodium
Alexander J. Blake +5 more
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A Hexameric Cationic Copper(II) Metallacrown as a Pertechnetate and Perrhenate Scavenger
Chemistry – A European Journal, 2015AbstractMaterials based on the cationic copper(II) hexanuclear 18‐membered metallacrown [18‐MC ‐6]6+ (2phH=2‐piconyl hydrazide) and tetrafluoroborate, perchlorate, nitrate, sulfate, and perrhenate anions were prepared by an easy method in aqueous medium.
Sabina Rodríguez‐Hermida +7 more
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Structural and Functional Evolution of Metallacrowns
Chemical Reviews, 2007Gellert, Mezei +2 more
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