Tapered Optical Fibers Coated with Rare-Earth Complexes for Quantum Applications. [PDF]
Mor OE +7 more
europepmc +1 more source
Ligand design for heterometallic 3d metallacrown complexes
Two decades of research on single molecule magnets (SMMs) led to multiple concepts to reach one of the most ambitious goals in molecular magnetism, a high energy barrier (Ueff ) for the magnetization reversal of a single molecule. This energy barrier is dependent on the spin ground state (S) and the axial magnetoanisotropy (D) of the molecule. Previous
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Crystal structure of an indium-salicyl-hydroximate complex cation: [In4(H2shi)8(H2O)6](NO3)4·8.57H2O. [PDF]
Aziz OA, Zeller M, Zaleski CM.
europepmc +1 more source
Pd(II)−N-heterocyclic carbene (NHC) metallacrown ether complexes have been synthesized for the first time. Reaction of bis(imidazolium) salts with a long polyether chain with Ag2O afforded silver−NHC complexes [Ag2(L)Cl2] 5, which reacted as carbene ...
Bin Rao (1626829) +3 more
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Hexa-μ-acetato-chlorido-(μ-N,2-dioxodo-benzene-1-carboximidato)-μ3-oxido-tetra-iron(III)-water (1/1) and hexa-μ-acetato-(μ-N,2-dioxodo-benzene-1-carboximidato)fluorido-μ3-oxido-tri-pyridine-tetra-iron(III)-pyridine-water (1/1/0.24). [PDF]
Ward CL, Allen MJ, Lutter JC.
europepmc +1 more source
Metal-organic cycle-based multistage assemblies. [PDF]
Sun Y, Tuo W, Stang PJ.
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Two new [12]metallacrown-6 compounds, [MII6(SMe)12] [M = Ru (1), Zn (2)], were constructed from a dimethyl sulfoxide decomposed methylthiol product to doubly bridged metal centers.
Ming-Hua Xie (1975657) +2 more
core +1 more source
Single-molecule magnets beyond a single lanthanide ion: the art of coupling. [PDF]
Chen YC, Tong ML.
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Metallacrowns: an ideal platform for accessing lanthanide luminescence
Metallacrowns (MCs) are a distinctive class of metallamacrocycles that serve as inorganic counterparts to the well-known crown ethers, in which the characteristic –[C–O–O]– repeating units are replaced by –[M–N–O]– motifs. Much like their organic analogues, the donor oxygen atoms within the MC framework can capture cations in the ...
Soroush Naseri, Vincent L. Pecoraro
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Discriminating between Parallel, Anti-Parallel and Hybrid G-Quadruplexes: Mechanistic Details on Their Binding to Small Molecules. [PDF]
Biver T.
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